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Dynamics of Thermoluminescence under Dual-Wavelength Vis–IR Laser Excitation of Eosin Molecules in a Polyvinyl Butyral Film Containing Oxygen and Silver Nanoparticles

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Abstract

Electronic and vibrational energy transfer processes taking place in molecular complexes in a polymer are investigated under dual-wavelength (visible at λ = 532 nm and IR at wavelength λ = 10.6 μm) laser photoexcitation of eosin molecules (С = 4 × 10–4 М) in air and without it (р ≈ 10–4 Torr) in thin polyvinyl butyral (PVB) films containing silver nanoparticles (R ≈ 36 nm) prepared by laser ablation. Generation of singlet oxygen, singlet–triplet annihilation, and enhancement of plasmon quenching of dye fluorescence are studied. Thermal-energy transfer processes in thin PVB films following pulsed IR excitation are simulated, and the temperature conductivity coefficients of the polymer films in the presence of silver nanoparticles are calculated. Low-temperature processes in PVB films containing dye molecules taking place after IR excitation are investigated, and the mechanism for accelerating intercombination S1 → Т1 transitions as a result of thermal heating and intramolecular vibrational-energy distribution is explained.

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REFERENCES

  1. V. S. Letokhov, Sov. Phys. Usp. 19, 149 (1976).

    Article  ADS  Google Scholar 

  2. F. Yang, L. Jiang, S. Wan, Zh. Cao, L. Liu, M. Wang, and Y. Lu, Opt. Laser Technol. 93, 194 (2017).

    Article  ADS  Google Scholar 

  3. D. Ciofini, I. Cacciari, and S. Siano, Measurement 122, 200 (2017).

    Google Scholar 

  4. A. A. Makarov, A. L. Malinovskii, and E. A. Ryabov, Phys. Usp. 55, 977 (2012).

    Article  ADS  Google Scholar 

  5. A. A. I. Khalil, Opt. Laser Technol. 75, 105 (2015).

    Article  ADS  Google Scholar 

  6. V. V. Komarov, A. M. Popova, I. O. Stureiko, L. Schmidt, and H. Jungclas, Mosc. Univ. Phys. Bull. 68, 339 (2013).

    Article  ADS  Google Scholar 

  7. G. N. Makarov, Phys. Usp. 60, 227 (2017).

    Article  ADS  Google Scholar 

  8. M. A. Odeneye and A. J. Stace, J Phys. Chem. Chem. Phys. 7, 998 (2005).

    Article  Google Scholar 

  9. S. L. Sobolev, Int. J. Heat Mass Transfer 94, 138 (2016).

    Article  Google Scholar 

  10. G. Du, Y. Wu, N. Uddin, Q. Yang, F. Chen, Y. Lu, H. Bian, and X. Hou, Opt. Commun. 375, 54 (2016).

    Article  ADS  Google Scholar 

  11. T. Ebato, M. Kayano, S. Sato, and N. Mikami, J. Phys. Chem. A 105, 8623 (2001).

    Article  Google Scholar 

  12. D. Nishijima, E. M. Hollmann, and R. P. Doerne, Spectrochim. Acta, Part A 124, 82 (2016).

    Article  ADS  Google Scholar 

  13. V. V. Klimov, Nanoplasmonics (Fizmtlit, Moscow, 2009; Pan Stanford, Singapore, 2011).

  14. S. A. Reitlinger, Permeability of Polymer Materials (Khimiya, Moscow, 1974) [in Russian].

    Google Scholar 

  15. I. Samusev, R. Borkunov, M. Tsarkov, E. Konstantinova, Y. Antipov, M. Demin, and V. Bryukhanov, J. Phys.: Conf. Ser. 961, 012011 (2018).

    Google Scholar 

  16. S. Gaponenko, Introduction to Nanophotonics (Cambridge Univ. Press, New York, 2010).

    Book  Google Scholar 

  17. V. V. Bryukhanov, B. F. Minaev, A. V. Tcibulnikova, N. S. Tikhomirova, and V. A. Slezhkin, J. Opt. Technol. 81, 625 (2014).

    Article  Google Scholar 

  18. N. Guillot, H. Shen, B. Fremaux, O. Peron, E. Rinnert, T. Toury, and M. Lany de la Chapelle, Appl. Phys. Lett. 97, 023113 (2010).

    Article  ADS  Google Scholar 

  19. B. F. Minaev, Russ. Chem. Rev. 76, 989 (2007).

    Article  Google Scholar 

  20. C. Schweitzer and R. Schmidt, Chem. Rev. 103, 1685 (2003).

    Article  Google Scholar 

  21. V. V. Bryukhanov, B. M. Minaev, A. V. Tsibul’nikova, and V. A. Slezhkin, Opt. Spectrosc. 119, 29 (2015).

    Article  ADS  Google Scholar 

  22. J. R. Lakowic, Principles of Fluorescence Spectroscopy (Springer Science, New York, 2006).

    Book  Google Scholar 

  23. C. A. Parker, Photoluminescence of Solutions (Elsevier, Amsterdam, 1968).

    Google Scholar 

  24. V. V. Ermolaev, Russ. Chem. Rev. 70, 471 (2001).

    Article  ADS  Google Scholar 

  25. A. Kh. Kuptsov and G. N. Zhizhin, Fourier Spectra of Raman Scattering and Infrared Absorption of Polymers (Fizmatlit, Moscow, 2001) [in Russian].

    Google Scholar 

  26. E. S. Medvedev and V. I. Osherov, Theory of Nonradiative Transitions in Polyatomic Molecules (Nauka, Moscow, 1983) [in Russian].

    Google Scholar 

  27. E. B. Sveshnikova and V. L. Ermolaev, Opt. Spectrosc. 111, 34 (2011).

    Article  ADS  Google Scholar 

  28. A. A. Ovchinnikov and N. S. Erikhman, Sov. Phys. Usp. 25, 738 (1982).

    Article  ADS  Google Scholar 

  29. A. V. Lykov, Theory of Heat Transfer (Vysshaya Shkola, Moscow, 1967) [in Russian].

    Google Scholar 

  30. L. N. Novichenok and Z. P. Shul’man, Thermophysical Properties of Polymers (Nauka Tekhnika, Minsk, 1971) [in Russian].

    Google Scholar 

  31. V. M. Agranovich and D. L. Mills, Surface Polaritons: Electromagnetic Waves at Surfaces and Interfaces (Nauka, Moscow, 1985; Elsevier Science, Amsterdam, 1982).

  32. B. F. Minaev, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 9, 12 (1978).

  33. M. D. Fernández, M. J. Fernández, and P. Hoces, J. Appl. Polym. Sci. 102, 5007 (2006).

    Article  Google Scholar 

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ACKNOWLEDGMENTS

Results reported in the present publication were obtained under state assignment no. 3.5022.2017/BCh of the Russian Ministry of Education and Science. Financial support from the 5 top 100 Russian Academic Excellence Project at the Immanuel Kant Baltic Federal University is acknowledged.

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Authors and Affiliations

  1. Kaliningrad State Technical University, 236022, Kaliningrad, Russia

    E. I. Konstantinova & Yu. N. Antipov

  2. Bogdan Khmelnitsky Cherkasy National University, 18031, Cherkasy, Ukraine

    B. F. Minaev

  3. Immanuel Kant Baltic Federal University, 236016, Kaliningrad, Russia

    E. I. Konstantinova, A. V. Tsibul’nikova, R. Yu. Borkunov, M. V. Tsar’kov, I. G. Samusev & V. V. Bryukhanov

Authors
  1. E. I. Konstantinova
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  2. B. F. Minaev
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  3. A. V. Tsibul’nikova
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  4. R. Yu. Borkunov
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  5. M. V. Tsar’kov
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  6. Yu. N. Antipov
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  7. I. G. Samusev
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  8. V. V. Bryukhanov
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Correspondence to E. I. Konstantinova or V. V. Bryukhanov.

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Translated by I. Shumai

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Konstantinova, E.I., Minaev, B.F., Tsibul’nikova, A.V. et al. Dynamics of Thermoluminescence under Dual-Wavelength Vis–IR Laser Excitation of Eosin Molecules in a Polyvinyl Butyral Film Containing Oxygen and Silver Nanoparticles. Opt. Spectrosc. 125, 874–881 (2018). https://doi.org/10.1134/S0030400X19020152

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  • DOI: https://doi.org/10.1134/S0030400X19020152

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