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Mechanofluorochromism and Thermofluorochromism of Boron Difluoride 3-Methylamino-1,3-diphenyl-2-propen-1-one

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Abstract

Mechanofluorochromism and thermofluorochromism of boron difluoride 3-methylamino-1,3-diphenyl-2-propen-1-one have been detected. Upon grinding of crystals, they exhibit a significant change in their excitation spectra. A dependence of the luminescence spectrum on the wavelength of the exciting light has been found, which indicates the occurrence of luminescence centers of two different structures. Upon heating of a grinding sample, a further evolution of its luminescence and excitation spectra has been observed. The mechanism of the observed effects has been proposed to be associated with dissociation and formation of J-aggregates.

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ACKNOWLEDGMENTS

This work was supported by the Russian Foundation for Basic Research, project no. 18-33-00281 mol_a.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia

    A. G. Mirochnik, G. O. Tretyakova & E. V. Fedorenko

  2. Far Eastern Federal University, 690091, Vladivostok, Russia

    G. O. Tretyakova, I. V. Svistunova & N. D. Podlozhnyuk

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  1. A. G. Mirochnik
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  2. G. O. Tretyakova
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  3. I. V. Svistunova
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  4. N. D. Podlozhnyuk
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  5. E. V. Fedorenko
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Correspondence to E. V. Fedorenko.

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Mirochnik, A.G., Tretyakova, G.O., Svistunova, I.V. et al. Mechanofluorochromism and Thermofluorochromism of Boron Difluoride 3-Methylamino-1,3-diphenyl-2-propen-1-one. Opt. Spectrosc. 125, 512–515 (2018). https://doi.org/10.1134/S0030400X18100168

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  • DOI: https://doi.org/10.1134/S0030400X18100168

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