Abstract
The photochemical behavior of boron difluoride 3-amino-1-phenyl-2-buten-1-one (I) and 3-methylamino-1-phenyl-2-buten-1-one (II) in polyethylene (PE) is comparatively studied. It is found that the photochemical behavior strongly depends on the crystal structure of complexes. UV irradiation of complex I in PE leads to luminescence quenching due to photodimerization. In samples kept in the dark, photodimers dissociate, which leads to an increase in the luminescence intensity of compound I compared to initial nonirradiated samples. In contrast to compound I, photolysis of II in PE revealed no noticeable changes in the luminescence intensity.
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A. G. Mirochnik, B. V. Bukvetskii, E. V. Gukhman, and V. E. Karasev, J. Fluoresc. 13, 157 (2003). doi 10.1023/A:1022939209971
B. V. Bukvetskii, E. V. Fedorenko, A. G. Mirochnik, and A. Yu. Beloliptsev, J. Struct. Chem. 51, 545 (2010). doi 10.1007/s10947-010-0079-y
Y. L. Chow and C. I. Johansson, J. Phys. Chem. 99, 17558 (1995).
Y. L. Chow and C. I. Johansson, J. Phys. Chem. 99, 17566 (1995).
E. V. Fedorenko, B. V. Bukvetskii, A. G. Mirochnik, D.H. Shlyk, M. V. Tkacheva, and A. A. Karpenko, J. Lumin. 130, 756 (2010). doi 10.1016/j.jlumin. 2009.11.027
A. G. Mirochnik, E. V. Fedorenko, and D. H. Shlik, Russ. J. Phys. Chem. 81, 1880 (2007). doi 10.1134/S0036024407110295
Y. Kubota, H. Hara, S. Tanaka, S. Funabiki, and M. Matsui, Org. Lett. 24, 6544 (2011). doi 10.1021/ol202819w
F. P. Macedo, C. Gwengo, S. V. Lindeman, M. D. Smith, and J. R. Gardinier, Eur. J. Inorg. Chem. 2008, 3200 (2008). doi 10.1002/ejic.200800243
G. O. Tretyakova, B. V. Bukvetskii, E. V. Fedorenko, A. Yu. Beloliptsev, and A. G. Mirochnik, Russ. Chem. Bull. 64, 2312 (2015). doi 10.1007/s11172-015-115
E. V. Fedorenko, G. O. Tretyakova, A. G. Mirochnik, A. Yu. Beloliptsev, I. V. Svistunova, V. A. Sazhnikov, and L. S. Atabekyan, J. Fluoresc., No. 26, 1839 (2016). doi 10.1007/s10895-016-1878-2
A. G. Mirochnik, E. V. Fedorenko, and D. Kh. Shlyk, Russ. Chem. Bull. 65, 806 (2016). doi 10.1007/s11172-016-1378-z
K. Itoh, M. Fujimoto, and M. Hashimoto, New J. Chem., No. 26, 1070 (2002). doi 10.1039/B110975H
G. M. J. Shmidt, Solid State Photochemistry (Chemie, Weinheim, New York, 1976).
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Original Russian Text © A.G. Mirochnik, A.V. Trifonov, E.V. Fedorenko, G.O. Tret’yakova, V.G. Kuryavyi, L.A. Lim, V.A. Reutov, 2017, published in Optika i Spektroskopiya, 2017, Vol. 123, No. 6, pp. 866–870.
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Mirochnik, A.G., Trifonov, A.V., Fedorenko, E.V. et al. The Luminescence and Photochemical Behavior of Boron Difluoride Ketoiminates. Opt. Spectrosc. 123, 871–874 (2017). https://doi.org/10.1134/S0030400X17120104
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DOI: https://doi.org/10.1134/S0030400X17120104