Abstract
The influence of the interference between IR spectral lines of water vapor on the atmospheric transmission has been studied. The calculations have shown that, for a relatively low pressure, the influence of the interference on the line shift is small for most water vapor lines. However, this influence can be significant for lines whose upper vibrational-rotational states are in a strong resonance. Thus, a relation exists between intramolecular resonances of different types, which manifest themselves as a result of an abnormally strong vibrational-rotational interaction and interference arising due to collisional distortion of molecular steady states. The interference between lines distorts the Lorentz shape of a line profile and leads to a nonlinear pressure dependence of the line shift and to an increased absorption in the atmospheric microwindows. The influence of the interference for a horizontal path is small: the largest addition is 3% at a frequency of 12414.07 cm−1. For a slant atmospheric path under summer conditions, the line interference contributes 0.5%, and for winter conditions the influence of the interference is about 1.5%. It is concluded that the line interference increases the absorption in the atmospheric microwindows.
Similar content being viewed by others
References
M. R. Cherkasov, Opt. Spektrosk. 40(1), 7 (1976)].
F. Thibault, These de Docteur en Sciences, l’universite Paris XI Orsay, 1992.
A. D. Bykov, N. N. Lavrent’eva, L. N. Sinitsa, and A. M. Solodov, Opt. Atmos. Okeana 14(9), 846 (2001).
A. Bykov, O. Naumenko, L. Sinitsa, et al., J. Mol. Spectrosc. 205(1), 1 (2001).
V. E. Zuev and V. S. Komarov, Statistical Models of Temperature and Gas Components of Atmosphere (Gidrometeoizdat, Leningrad, 1986) [in Russian].
I. I. Ippolitov, V. S. Komarov, and A. A. Mitsel’, in Spectroscopic Methods of Sounding of Atmosphere, Ed. by I. V. Samokhvalov (Nauka, Novosibirsk, 1985) [in Russian].
Author information
Authors and Affiliations
Additional information
Original Russian Text © A.D. Bykov, N.N. Lavrent’eva, T.P. Mishina, L.N. Sinitsa, 2008, published in Optika i Spektroskopiya, 2008, Vol. 104, No. 2, pp. 198–204.
Rights and permissions
About this article
Cite this article
Bykov, A.D., Lavrent’eva, N.N., Mishina, T.P. et al. Influence of the interference between water vapor lines on the atmospheric transmission of near-IR radiation. Opt. Spectrosc. 104, 165–171 (2008). https://doi.org/10.1134/S0030400X08020033
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0030400X08020033