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Study of Nickel Catalysts Supported on MnOx–CeO2 Mixed Oxides in Dry Reforming of Methane

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Abstract

Nickel-containing (10 wt % Ni) catalysts supported on CeO2–MnOх oxides with different Ce/Mn ratios (0.25, 1, and 9) have been synthesized and studied in dry reforming of methane (DRM). The low-temperature N2 sorption, XRD, and H2-TPR methods have been used to study the effect of the Ce/Mn ratio on the phase composition of the catalysts and the size and distribution of the Ni-containing oxide precursor to determine the role of MnOx phases and the Ce1 − xMnxO2 − δ solid solution in the formation of the active surface of the catalysts. The addition of manganese oxide contributes to the incorporation of Nin+ cations into the surface structure to form solid solutions, which leads to a decrease in the size of NiO crystallites on the support surface. The synthesized catalysts have been studied in the DRM process in the long-run temperature testing mode for 24 h. The catalyst based on a support with a Ce/Mn weight ratio of 0.25 has exhibited the highest activity and stability in DRM (X(CH4)/X(CO2) = 47/70); this fact has been attributed to the existence of a developed MnOx interface and the presence of fine Ni and MnNiOx particles on the surface.

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Funding

This work was supported by a project of the Russian Science Foundation (agreement no. 19-73-30026).

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Authors and Affiliations

  1. Tomsk State University, 634050, Tomsk, Russia

    M. V. Grabchenko, N. V. Dorofeeva, I. N. Lapin & O. V. Vodyankina

  2. Istituto per lo Studio dei Materiali Nanostrutturati (ISMN)-CNR, 90146, Palermo, Italy

    V. La Parola & L. F. Liotta

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  1. M. V. Grabchenko
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  2. N. V. Dorofeeva
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  3. I. N. Lapin
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  6. O. V. Vodyankina
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Correspondence to M. V. Grabchenko.

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Translated by M. Timoshinina

Abbreviations and notation: DRM, dry reforming of methane; H2-TPR, temperature-programmed reduction with hydrogen; XRF, X-ray fluorescence analysis; Ssp, specific surface area; BET, Brunauer–Emmett–Teller method; BJH, Barrett–Joyner–Halenda method; XRD, X-ray diffraction analysis; TPO, temperature-programmed oxidation; TGA, thermogravimetric analysis; CSR, coherent scattering region; NPs, nanoparticles.

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Grabchenko, M.V., Dorofeeva, N.V., Lapin, I.N. et al. Study of Nickel Catalysts Supported on MnOx–CeO2 Mixed Oxides in Dry Reforming of Methane. Kinet Catal 62, 765–777 (2021). https://doi.org/10.1134/S0023158421060069

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  • DOI: https://doi.org/10.1134/S0023158421060069

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