Skip to main content
SpringerLink
Log in

Decomposition of Formic Acid on Pt/N-Graphene

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The properties of a new catalytic Pt/N-graphene system in the gas-phase reaction of formic acid decomposition for the production of pure hydrogen were studied. Graphene powders undoped and doped with nitrogen atoms were used as carbon supports. Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (TEM), and the chemisorption of CO were used to characterize the synthesized catalysts. It was found that the activity of the catalysts increased upon graphene doping with nitrogen atoms and with increasing the platinum concentration from 0.2 to 1 wt %; the catalyst selectivity in the test reaction was as high as 96–99%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. Grasemann, M. and Laurenczy, G., Energy Environ. Sci., 2012, vol. 5, p. 8171.

    Article  CAS  Google Scholar 

  2. Bulushev, D.A. and Ross, J.R.H., ChemSusChem, 2018, vol. 11, p. 821.

    Article  CAS  Google Scholar 

  3. Tang, C., Surkus, A.E., Pohl, M.M., Agostini, G., Schneider, M., Junge, H., and Beller, M., Angew. Chem., Int. Ed., 2017, vol. 56, p. 16616.

    Article  CAS  Google Scholar 

  4. Jia, L., Bulushev, D.A., Podyacheva, O.Yu., Boronin, A.I., Kibis, L.S., Gerasimov, E.Yu., Beloshapkin, S., Seryak, I.A., Ismagilov, Z.R., and Ross, J.R.H., J. Catal., 2013, vol. 307, p. 94.

    Article  CAS  Google Scholar 

  5. Ayusheev, A.B., Taran, O.P., Seryak, I.A., Podyacheva, O.Yu., Descorme, C., Besson, M., Kibis, L.S., Boronin, A.I., Romanenko, A.I., Ismagilov, Z.R., and Parmon, V.N., Appl. Catal., B, 2014, vol. 146, p. 177.

    Article  CAS  Google Scholar 

  6. Ismagilov, Z.R., Kuntsevich, S.V., Kuznetsov, V.V., Shikina, N.V., Kerzhentsev, M.A., Rogov, V.A., and Ushakov, V.A. Kinet. Catal., 2007, vol. 48, no. 4, p. 511.

    Article  CAS  Google Scholar 

  7. Podyacheva, O.Yu. and Ismagilov, Z.R., Catal. Today, 2015, vol. 249, p. 12.

    Article  CAS  Google Scholar 

  8. Zacharska, M., Bulusheva, L.G., Lisitsyn, A.S., Beloshapkin, S., Guo, Y., Chuvilin, A.L., Shlyakhova, E.V., Podyacheva, O.Y., Leahy, J.J., Okotrub, A.V., and Bulushev, D.A., ChemSusChem, 2017, vol. 10, p. 720.

    Article  CAS  Google Scholar 

  9. Chesnokov, V.V., Prosvirin, I.P., Zaikovskii, V.I., and Zaitseva, N.A., Eurasian Chem. Technol. J., 2003, vol. 5, no. 2, p. 127.

    Article  CAS  Google Scholar 

  10. Kochubey, D.I., Chesnokov, V.V., and Malykhin, S.E., Carbon, 2012, vol. 50, no. 8, p. 2782.

    Article  CAS  Google Scholar 

  11. Chesnokov, V.V., Kriventsov, V.V., Malykhin, S.E., Chichkan, A.S., and Podyacheva, O.Y., J. Struct. Chem., 2018, vol. 59, no. 4, p. 839.

    Article  CAS  Google Scholar 

  12. Chesnokov, V.V., Kriventsov, V.V., Malykhin, S.E., Svintsitskiy, D.A., Podyacheva, O.Y., Lisitsyn, A.S., and Richards, R.M., Diam. Relat. Mater., 2018, vol. 89, p. 67.

    Article  CAS  Google Scholar 

  13. Bulushev, D.A., Zacharska, M., Lisitsyn, A.S., Podyacheva, O.Y., Hage, F.S., Ramasse, Q.M., Bangert, U., and Bulusheva, L.G., ACS Catal., 2016, vol. 6, p. 3442.

    Article  CAS  Google Scholar 

  14. Zacharska, M., Podyacheva, O.Y., Kibis, L.S., Boronin, A.I., Senkovskiy, B.V., Gerasimov, E.Y., Taran, O.P., Ayusheev, A.B., Parmon, V.N., Leahy, J.J., and Bulushev, D.A., ChemCatChem, 2015, vol. 7, p. 2910.

    Article  CAS  Google Scholar 

  15. Golub, F.S., Beloshapkin, S., Gusel’nikov, A.V., Bolotov, V.A., Parmon, V.N., and Bulushev, D.A., Energies, 2019, vol. 12, no. 20, p. 3885.

    Article  CAS  Google Scholar 

  16. Huang, C., Li, C., and Shi, G., Energy Environ. Sci., 2012, vol. 5, p. 8848.

    Article  CAS  Google Scholar 

  17. Luo, Q., Zhang, W., Fu, C. F., and Yang, J., Int. J. Hydrogen Energy, 2018, vol. 43, p. 6997.

    Article  CAS  Google Scholar 

  18. Jeyakumar, T.C. and Sivasankar, C., New J. Chem., 2019, vol. 43, p. 1440.

    Article  Google Scholar 

  19. Feng, J.R. and Wang, G.C., Appl. Surf. Sci., 2021, vol. 539, p. 148192:1-10.

  20. Grad, O., Mihet, M., Dan, M., Blanita, G., Radu, T., Berghian-Grosan, C., and Lazar, M.D., J. Mater. Sci., 2019, vol. 54, p. 6991.

    Article  CAS  Google Scholar 

  21. Li, S.J., Ping, Y., Yan, J.M., Wang, H.L., Wu, M., and Jiang, Q., J. Mater. Chem. A, 2015, vol. 3, p. 14535.

    Article  CAS  Google Scholar 

  22. Zhao, X., Dai, P., Xu, D., Li, Z., and Guo, Q., Int. J. Hydrogen Energy, 2020, vol. 45, p. 30396.

    Article  CAS  Google Scholar 

  23. Yan, J.M., Li, S.J., Yi, S.S., Wulan, B.R., Zheng, W.T., and Jiang, Q., Adv. Mater., 2018, vol. 30, p. 1703038.

    Article  Google Scholar 

  24. Kruse, N., McEwen, J.S., Park, J.C., and Ha, S., Appl. Catal., B, 2020, vol. 264, p. 118478:1-12.

  25. Chesnokov, V.V., Chichkan’, A.S., Bedilo, A.F., Shuvarakova, E.I., and Parmon, V.N., Dokl. Phys. Chem., 2019, vol. 488, no. 5, p. 154.

    Article  CAS  Google Scholar 

  26. Buyanov, R.A., Zakoksovanie katalizatorov (Coking of Catalysts), Moscow: Nauka, 1983, p. 207.

  27. Gor, G.Yu., Thommes, M., Cychosz, K.A., and Neimark, A.V., Carbon, 2012, vol. 50, p. 1583.

    Article  CAS  Google Scholar 

  28. Thommes, M., Kaneko, K., Neimark, A.V., Olivier, J.P., Rodriguez-Reinoso, F., Rouquerol, J., and Sing, K.S.W., Pure Appl. Chem., 2015, vol. 87, p. 1051.

    Article  CAS  Google Scholar 

  29. http://xpspeak.software.informer.com/4.1/.

  30. Sadezky, A., Muckenhuber, H., Grothe, H., Niessner, R., and Pöschl, U., Carbon, 2005, vol. 43, p. 1731.

    Article  CAS  Google Scholar 

  31. Podyacheva, O.Yu., Suboch, A.N., Bokova-Sirosh, S.N., Romanenko, A.I., Kibis, L.S., Obraztsova, E.D., and Kuznetsov, V.L., Phys. Status Solidi B, 2018, vol. 255, p. 1700253

    Article  Google Scholar 

  32. Chesnokov, V.V., Chichkan, A.S., Paukshtis, E.A., Svintsitskiy, D.A., Ismagilov, Z.R., Parmon, V.N., Dokl. Phys. Chem., 2017, vol. 476, no. 2, p. 186.

    Article  CAS  Google Scholar 

  33. Arrigo, R., Schuster, M.E., Xie, Z., Yi, Y., Wowsnick, G., Sun, L.L., Hermann, K.E., Friedrich, M., Kast, P., Hävecker, M., Knop-Gericke, A., and Schlögl, R., ACS Catal., 2015, vol. 5, p. 2740.

    Article  CAS  Google Scholar 

  34. Shao, Y., Zhang, S., Engelhard, M.H., Li, G., Shao, G., Wang, Y., Liu, J., Aksay, I.A., and Lin, Y., J. Mater. Chem., 2010, vol. 20, p. 7491.

    Article  CAS  Google Scholar 

  35. Li, D., Yu, C., Wang, M., Zhang, Y., and Pan, C., RSC Adv., 2014, vol. 4, p. 55394.

    Article  CAS  Google Scholar 

  36. Santiago, S.R.M., Wong, Y.-A., Lin, T.-N., Chang, C.-H., Yuan, C.-T., and Shen, J.-L., Optics Lett., 2017, vol. 42, p. 3642.

    Article  CAS  Google Scholar 

  37. Guo, L., Jiang, W.-J., Zhang, Y., Hu, J.-S., Wei, Z.-D., and Wan, L.-J., ACS Catal., 2015, vol. 5, p. 2903.

    Article  CAS  Google Scholar 

  38. Ma, J., Habrioux, A., Luo, Y., Ramos-Sanchez, G., Calvillo, L., Granozzi, G., Balbuena, P.B., and Alonso-Vante, N., J. Mater. Chem. A, 2015, vol. 3, p. 11891.

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The Raman spectroscopic experiments were carried out using the equipment of the Scientific and Educational Center Molecular Design and Environmentally Safe Technologies, Novosibirsk State University.

Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of a state contract of the Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences (project no. AAAA-A21-121011390054-1).

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    V. V. Chesnokov, A. S. Lisitsyn, V. I. Sobolev, E. Yu. Gerasimov, I. P. Prosvirin, Yu. A. Chesalov, A. S. Chichkan & O. Yu. Podyacheva

Authors
  1. V. V. Chesnokov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. S. Lisitsyn
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. I. Sobolev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. Yu. Gerasimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. P. Prosvirin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Yu. A. Chesalov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. S. Chichkan
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. O. Yu. Podyacheva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. V. Chesnokov.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by V. Makhlyarchuk

Abbreviations and designations: XPS, X-ray photoelectron spectroscopy; HRTEM, high-resolution transmission electron microscopy.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chesnokov, V.V., Lisitsyn, A.S., Sobolev, V.I. et al. Decomposition of Formic Acid on Pt/N-Graphene. Kinet Catal 62, 518–527 (2021). https://doi.org/10.1134/S0023158421040017

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158421040017

Keywords:

Search

Navigation