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Catalytic Cracking of Cyclohexane and 1-Hexene Mixtures on Mono-, Bi-, and Tri-Zeolite Catalysts

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Abstract

The effects of temperature (540–640°C), weight hour space velocity (1.0–7.0 h–1), and steam : raw material ratios (0–2.5) on the yield of C2–C4 olefins, conversion, and octane characteristics in the cracking of a mixture of model hydrocarbons (cyclohexane and 1-hexene) were studied. The influence of the structure of zeolites in mono-, bi-, and tri-zeolite catalysts on the distribution of cracking products was examined. It was found that the combination of catalyst components in bi- and tri-zeolite systems makes it possible to increase the efficiency of the consecutive cracking of hydrocarbons (C6–C12 → C4–C8 → C3–C6 → C2–C4) according to the following reaction scheme: matrix → ZSM-5 → FER. The maximum total yield of C2–C4 olefins (50.2 wt % at a conversion of 75.5%) was achieved with the use of a bi-zeolite catalyst of ZSM-5 + FER.

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ACKNOWLEDGMENTS

This work was performed at the Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences in accordance with a research program V.46 for 2013–2020 (project no. V.46.2.4; state registration no. AAAA-A17-117021450095-1).

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, 644040, Omsk, Russia

    O. V. Potapenko, M. S. Khudyakov, E. O. Altynkovich, K. S. Plekhova, T. P. Sorokina & V. P. Doronin

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  1. O. V. Potapenko
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  2. M. S. Khudyakov
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  3. E. O. Altynkovich
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  4. K. S. Plekhova
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  5. T. P. Sorokina
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  6. V. P. Doronin
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Correspondence to O. V. Potapenko.

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Translated by V. Makhlyarchuk

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Potapenko, O.V., Khudyakov, M.S., Altynkovich, E.O. et al. Catalytic Cracking of Cyclohexane and 1-Hexene Mixtures on Mono-, Bi-, and Tri-Zeolite Catalysts. Kinet Catal 60, 74–86 (2019). https://doi.org/10.1134/S0023158419010117

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  • DOI: https://doi.org/10.1134/S0023158419010117

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