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Kinetics and Catalysis

, Volume 59, Issue 2, pp 150–159 | Cite as

The Oxidation of Carbon Monoxide as an Integrated Part of the Coupled Alkane Oxidation Process: Gas-Phase Oxidation over Supported Metal-Complex Catalysts

  • E. G. Chepaikin
  • A. P. Bezruchenko
  • G. N. Menchikova
  • O. P. Tkachenko
  • L. M. Kustov
  • A. V. Kulikov
Article
  • 19 Downloads

Abstract

Heterogeneous rhodium–copper chloride catalysts for gas-phase oxidation processes were prepared via the cold impregnation of γ-Al2O3 with aqueous RhCl3 and CuCl2 solutions. Heptafluorobutyric or pentafluorobenzoic acids were additionally deposited onto these catalysts to simulate the action of homogeneous rhodium–copper chloride catalytic systems in the coupled alkane–carbon monoxide oxidation reaction. The catalysts were studied in the reactions of carbon monoxide oxidation and coupled propane–CO oxidation with dioxygen by diffuse reflectance IR Fourier transform spectroscopy (DRIFTS) and electron paramagnetic resonance (EPR). The obtained data indicate the probable transfer of electrons between rhodium and copper compounds.

Keywords

carbon monoxide catalytic oxidation rhodium chloride copper chloride γ-aluminum oxide DRIFTS EPR 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • E. G. Chepaikin
    • 1
  • A. P. Bezruchenko
    • 1
  • G. N. Menchikova
    • 1
  • O. P. Tkachenko
    • 2
  • L. M. Kustov
    • 2
    • 3
  • A. V. Kulikov
    • 4
  1. 1.Merzhanov Institute of Structural Macrokinetics and Materials ScienceRussian Academy of SciencesChernogolovka, Moscow oblastRussia
  2. 2.Zelinskii Institute of Organic ChemistryRussian Academy of SciencesMoscowRussia
  3. 3.Department of ChemistryMoscow State UniversityMoscowRussia
  4. 4.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia

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