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The Oxidation of Carbon Monoxide as an Integrated Part of the Coupled Alkane Oxidation Process: Gas-Phase Oxidation over Supported Metal-Complex Catalysts

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Abstract

Heterogeneous rhodium–copper chloride catalysts for gas-phase oxidation processes were prepared via the cold impregnation of γ-Al2O3 with aqueous RhCl3 and CuCl2 solutions. Heptafluorobutyric or pentafluorobenzoic acids were additionally deposited onto these catalysts to simulate the action of homogeneous rhodium–copper chloride catalytic systems in the coupled alkane–carbon monoxide oxidation reaction. The catalysts were studied in the reactions of carbon monoxide oxidation and coupled propane–CO oxidation with dioxygen by diffuse reflectance IR Fourier transform spectroscopy (DRIFTS) and electron paramagnetic resonance (EPR). The obtained data indicate the probable transfer of electrons between rhodium and copper compounds.

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Authors and Affiliations

  1. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    E. G. Chepaikin, A. P. Bezruchenko & G. N. Menchikova

  2. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    O. P. Tkachenko & L. M. Kustov

  3. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    L. M. Kustov

  4. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    A. V. Kulikov

Authors
  1. E. G. Chepaikin
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  2. A. P. Bezruchenko
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  3. G. N. Menchikova
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  4. O. P. Tkachenko
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  5. L. M. Kustov
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  6. A. V. Kulikov
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Correspondence to E. G. Chepaikin.

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Original Russian Text © E.G. Chepaikin, A.P. Bezruchenko, G.N. Menchikova, O.P. Tkachenko, L.M. Kustov, A.V. Kulikov, 2018, published in Kinetika i Kataliz, 2018, Vol. 59, No. 2, pp. 177–187.

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Chepaikin, E.G., Bezruchenko, A.P., Menchikova, G.N. et al. The Oxidation of Carbon Monoxide as an Integrated Part of the Coupled Alkane Oxidation Process: Gas-Phase Oxidation over Supported Metal-Complex Catalysts. Kinet Catal 59, 150–159 (2018). https://doi.org/10.1134/S0023158418020039

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  • DOI: https://doi.org/10.1134/S0023158418020039

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