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Preparation of platinum-containing hydrogenation catalysts supported on thermally reduced graphite oxide

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Abstract

Graphene-like materials with an atomic ratio of C/O > 40 have been prepared by calcination of graphite oxide (C/O = 1.46) in an inert atmosphere. Platinum nanoparticles (average size of ~2.0 nm) have been deposited onto the surface of the materials from an aqueous solution of H2PtCl6 · xH2O in the presence of pyridine. These particles catalyze the liquid-phase hydrogenation of PhNO2 to PhNH2 and that of the double bonds in 1-decene and styrene. As a support, the defect-containing graphene-like material prepared by calcination of graphite oxide at 1000–1050°C for 3 h has certain advantages over graphite oxide reduced by chemical means or by short-term heating. This material and catalysts supported on it can be formed as “carbon paper” by vacuum filtration.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    S. D. Kushch, N. S. Kuyunko & A. A. Arbuzov

  2. Institute of Experimental Mineralogy, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    G. V. Bondarenko

Authors
  1. S. D. Kushch
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  2. N. S. Kuyunko
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  3. A. A. Arbuzov
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  4. G. V. Bondarenko
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Correspondence to S. D. Kushch.

Additional information

Original Russian Text © S.D. Kushch, N.S. Kuyunko, A.A. Arbuzov, G.V. Bondarenko, 2015, published in Kinetika i Kataliz, 2015, Vol. 56, No. 6, pp. 808–815.

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Kushch, S.D., Kuyunko, N.S., Arbuzov, A.A. et al. Preparation of platinum-containing hydrogenation catalysts supported on thermally reduced graphite oxide. Kinet Catal 56, 818–825 (2015). https://doi.org/10.1134/S0023158415060075

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  • DOI: https://doi.org/10.1134/S0023158415060075

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