Abstract
The kinetics and mechanism of water oxidation with cerium(IV) compounds catalyzed by a tetranuclear ruthenium complex containing two polyoxotungstate ligands are reported. Four water molecules are oxidized via an eight-electron process to form two oxygen molecules.
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Dzhabiev, T.S. and Shilov, A.E., Russ. Chem. Rev., 2012, vol. 81, no. 12, p. 1146.
Sartorel, A., Carraro, M., Scorrano, G., De Zorzi, R., Geremia, S., McDaniel, N.D., Bernhard, S., and Bonchio, M., J. Am. Chem. Soc., 2008, vol. 130, p. 5006.
Geletii, Y.V., Botar, B., Kogerler, P., Hillesheim, D.A., Musaev, D.G., and Hill, C.L., Angew. Chem., Int. Ed. Engl., 2008, vol. 47, p. 3896.
Geletii, Y.V., Huang, Z., Hou, Y., Musaev, D.G., Lian, T., and Hill, C.L., J. Am. Chem. Soc., 2009, vol. 131, p. 7522.
Cao, R., Ma, H., Geletii, Y.V., Hardcastle, K.I., and Hill, C.L., Inorg. Chem., 2009, vol. 48, p. 5596.
Sala, X., Romero, L., Rodriguez, M., Escriche, L., and Llobet, A., Angew. Chem., Int. Ed. Engl., 2009, vol. 48, p. 2842.
Huang, Z., Luo, Z., Geletii, Y.V., Vickers, J.W., Yin, Q., Wu, D., Hou, Y., Ding, Y., Song, J., Musaev, D.G., Hill, C.L., and Lian, T., J. Am. Chem. Soc., 2011, vol. 133, p. 2068.
Yin, Q., Tan, J.M., Besson, C., Geletii, Y.V., Musaev, D.G., Kuznetsov, A.E., Luo, Z., Hardcastle, K.I., and Hill, C.L., Science, 2010, vol. 328, p. 342.
Besson, C., Huang, Z., Geletii, Y.V., Lense, S., Hardcastle, K.I., Musaev, D.G., Lian, T., Proust, A., and Hill, C.L., Chem. Commun., 2010, vol. 46, p. 2784.
Hurst, J.K., Science, 2010, vol. 328, p. 315.
Lieb, D., Zahl, A., Wilson, E.F., Streb, C., Nye, L.C., Meyer, K., and Ivanovic-Burmazovic, I., Inorg. Chem., 2011, vol. 50, p. 9053.
Suss-Fink, G., Angew. Chem., Int. Ed. Engl., 2008, vol. 47, p. 5888.
Howells, A.R., Sankarraj, A., and Shannon, C., J. Am. Chem. Soc., 2004, vol. 126, p. 12258.
Pleskov, Yu.V., Russ. J. Electrochem., 2011, vol. 47, no. 7, p. 869.
Teze, A. and Herve, G., Inorg. Synth., 1990, vol. 27, p. 85.
Rong, C. and Pope, M.T., J. Am. Chem. Soc., 1992, vol. 114, p. 2932.
Cacace, F., de Petris, G., and Troiani, A., Angew. Chem., Int. Ed. Engl., 2001, vol. 40, p. 4062.
Shmatko, N. and Dzhabieva, Z., Khimicheskoe modelirovanie fermenta, okislyayushchego vodu v fotosisteme II (Chemical Modeling of the Enzyme Oxidizing Water in Photosystem II), Saarbrücken: Lambert Academic, 2012.
Concepcion, J.J., Jurss, J.W., Templeton, J.L., and Meyer, T.J., J. Am. Chem. Soc., 2008, vol. 130, p. 16462.
Bozoglian, F., Romain, S., Ertem, M.Z., Todorova, T.K., Sens, C., Mola, J., Rodriguez, M., Romero, L., Benetbuchholz, J., Fontrodona, X., Cramer, C.J., Gagliardi, L., and Llobet, A., J. Am. Chem. Soc., 2009, vol. 131, p. 15176.
Zamolodchikov, D.G., Herald Russ. Acad. Sci., 2006, vol. 76, no. 3, p. 209.
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Original Russian Text © Z.M. Dzhabieva, O.V. Yakutkina, T.S. Dzhabiev, A.E. Shilov, 2014, published in Kinetika i Kataliz, 2014, Vol. 55, No. 4, pp. 444–449.
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Dzhabieva, Z.M., Yakutkina, O.V., Dzhabiev, T.S. et al. Kinetics of water oxidation with cerium(IV) compounds catalyzed by a tetranuclear ruthenium complex. Kinet Catal 55, 422–427 (2014). https://doi.org/10.1134/S002315841404003X
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DOI: https://doi.org/10.1134/S002315841404003X