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Kinetics of water oxidation with cerium(IV) compounds catalyzed by a tetranuclear ruthenium complex

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Abstract

The kinetics and mechanism of water oxidation with cerium(IV) compounds catalyzed by a tetranuclear ruthenium complex containing two polyoxotungstate ligands are reported. Four water molecules are oxidized via an eight-electron process to form two oxygen molecules.

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Correspondence to T. S. Dzhabiev.

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Original Russian Text © Z.M. Dzhabieva, O.V. Yakutkina, T.S. Dzhabiev, A.E. Shilov, 2014, published in Kinetika i Kataliz, 2014, Vol. 55, No. 4, pp. 444–449.

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Dzhabieva, Z.M., Yakutkina, O.V., Dzhabiev, T.S. et al. Kinetics of water oxidation with cerium(IV) compounds catalyzed by a tetranuclear ruthenium complex. Kinet Catal 55, 422–427 (2014). https://doi.org/10.1134/S002315841404003X

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  • DOI: https://doi.org/10.1134/S002315841404003X

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