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Nocturnal chemistry of sulfur dioxide in drops of tropospheric clouds

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Abstract

The dynamics of sulfur dioxide oxidation by oxygen in tropospheric clouds at night is analyzed. A crucial role in this free-radical process is played by the uptake of “nocturnal” NO3 radicals from the gas phase. Size effects in chemical reactions involving nocturnal NO3 have been discovered.

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References

  1. Warneck, P., Mirabel, P., Salmon, G.A., van Eldik, R., Vinckier, C., Wannowius, K.J., and Zetsch, C., in Review of the Activities and Achievements of the EUROTRAC Subproject HALIPP: Heterogeneous and Liquid Phase Processes, Warneck, P., Ed., Berlin: Springer, 1996, p. 7.

  2. Choularton, T.W., Colville, R.N., Bower, K.N., Gallagher, M.W., Wells, M., Beswick, K.M., Arends, B.G., Mols, J.J., Kos, G.P.A., and Fuzzi, S., Atmos. Environ., 1997, vol. 31, no. 16, p. 2393.

    Article  CAS  Google Scholar 

  3. Seinfeld, J.H. and Pandis, S.N., Atmospheric Chemistry and Physics: From Air Pollution to Climate Change, New York: Wiley-Interscience, 1998.

    Google Scholar 

  4. Hayon, E., Treinin, A., and Wilf, J., J. Am. Chem. Soc., 1972, vol. 94, p. 47.

    Article  CAS  Google Scholar 

  5. Ziajka, J., Beer, F., and Warneck, P., Atmos. Environ., 1994, vol. 28, p. 2549.

    Article  CAS  Google Scholar 

  6. Benkelberg, H.-J. and Warneck, P., J. Phys. Chem., 1995, vol. 99, p. 5214.

    Article  CAS  Google Scholar 

  7. Chameides, W.L. and Davis, D.D., J. Geophys. Res., 1982, vol. 87, p. 4836.

    Article  Google Scholar 

  8. Ermakov, A.N., Larin, I.K., Ugarov, A.A., and Purmal’, A.P., Kinet. Catal., 2006, vol. 47, no. 6, p. 849.

    Google Scholar 

  9. Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling, Jet Propulsion Laboratory Publication, Evaluation Number 12, 2006.

  10. Mauldin, R.L., Mandronich, S., and Flocke, S.J., Geophys. Rev. Lett., 1997, vol. 24, p. 3033.

    Article  CAS  Google Scholar 

  11. Berdnikov, V.M. and Bazhin, N.M., Zh. Fiz. Khim., 1970, vol. 44, p. 395.

    Google Scholar 

  12. Stanbury, D.M., Adv. Inorg. Chem., 1989, vol. 34, p. 69.

    Article  Google Scholar 

  13. Knollenberg, R.G., in Clouds: Their Formation, Optical Properties and Effects, Hobbs, P.V. and Deepak, A., Eds., New York: Academic, 1981, p. 15.

  14. Schwartz, S.E., in Chemistry of Multiphase Atmospheric Systems, NATO ASI Series, Jaeschke, W., Ed., Berlin: Springer, 1986, p. 415.

  15. Herrmann, H., Ervens, B., Jacobi, H.-W., Wolke, R., Nowacki, P., and Zellner, R., J. Atmos. Chem., 2000, vol. 36, p. 231.

    Article  CAS  Google Scholar 

  16. Sander, R., Compilations of Henry’s Law Constants for Inorganic and Organic Species of Potential Importance in Environmental Chemistry, Version 3, http://www.mpch-mainz.mpg.de/~sander/res/henry.html. Cited April 8, 1999.

    Google Scholar 

  17. Schwartz, S.E. and Freiberg, J.E., Atmos. Environ., 1981, vol. 15, p. 1129.

    Article  CAS  Google Scholar 

  18. Exner, M., Herrmann, H., and Zellner, R., Ber. Bunsen-Ges. Phys. Chem., 1992, vol. 96, p. 470.

    Article  CAS  Google Scholar 

  19. George, C., Ponche, J.L., Mirabel, P., Behnke, W., and Scheer, V., J. Phys. Chem., 1994, vol. 98, p. 8780.

    Article  CAS  Google Scholar 

  20. Huie, R.E., Clifton, C.L., and Altstein, N., Radiat. Phys. Chem., 1989, vol. 33, no. 4, p. 361.

    CAS  Google Scholar 

  21. Betterton, E.A. and Hoffmann, M.R., J. Phys. Chem., 1988, vol. 92, no. 21, p. 5962.

    Article  CAS  Google Scholar 

  22. Yermakov, A.N., Zhitomirsky, B.M., Poskrebyshev, G.A., and Sosurakov, D.M., J. Phys. Chem., 1993, vol. 97, no. 41, p. 10712.

    Article  CAS  Google Scholar 

  23. Wine, P.H., Tang, Y., Thorn, R.P., and Wells, J.R., J. Geophys. Res. D: Atmos., 1989, vol. 94, no. 1, p. 1085.

    Article  CAS  Google Scholar 

  24. Yermakov, A.N., Zhitomirsky, B.M., Poskrebyshev, G.A., and Stoliarov, S.I., J. Phys. Chem., 1995, vol. 99, no. 10, p. 3120.

    Article  CAS  Google Scholar 

  25. Hoffman, M.R., Atmos. Environ., 1986, vol. 20, p. 1145.

    Article  Google Scholar 

  26. Laj, P., Fuzzi, S., Lazzari, A., Ricci, L., and Orsi, G., Atmos. Environ., 1997, vol. 31, no. 16, p. 2503.

    Article  CAS  Google Scholar 

  27. Laj, P., Fuzzi, S., Facchini, M.C., Lind, J.A., Orsi, G., Preiss, M., Maser, R., Jaeschke, W., Seyffer, E., Helaq, G., Acker, K., Wieprecht, W., Moller, D., Arends, B.G., Mols, G.G., Colvill, R.N., Galagher, M.W., Beswick, K.M., Hargreaves, K.J., Storetonwest, R.L., and Sutton, M.A., Atmos. Environ., 1997, vol. 31, no. 16, p. 2589.

    Article  CAS  Google Scholar 

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Correspondence to I. K. Larin.

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Original Russian Text © A.N. Yermakov, I.K. Larin, 2013, published in Kinetika i Kataliz, 2013, Vol. 54, No. 3, pp. 275–281.

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Yermakov, A.N., Larin, I.K. Nocturnal chemistry of sulfur dioxide in drops of tropospheric clouds. Kinet Catal 54, 263–269 (2013). https://doi.org/10.1134/S0023158413030038

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