Abstract
The dynamics of sulfur dioxide oxidation by oxygen in tropospheric clouds at night is analyzed. A crucial role in this free-radical process is played by the uptake of “nocturnal” NO3 radicals from the gas phase. Size effects in chemical reactions involving nocturnal NO3 have been discovered.
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Warneck, P., Mirabel, P., Salmon, G.A., van Eldik, R., Vinckier, C., Wannowius, K.J., and Zetsch, C., in Review of the Activities and Achievements of the EUROTRAC Subproject HALIPP: Heterogeneous and Liquid Phase Processes, Warneck, P., Ed., Berlin: Springer, 1996, p. 7.
Choularton, T.W., Colville, R.N., Bower, K.N., Gallagher, M.W., Wells, M., Beswick, K.M., Arends, B.G., Mols, J.J., Kos, G.P.A., and Fuzzi, S., Atmos. Environ., 1997, vol. 31, no. 16, p. 2393.
Seinfeld, J.H. and Pandis, S.N., Atmospheric Chemistry and Physics: From Air Pollution to Climate Change, New York: Wiley-Interscience, 1998.
Hayon, E., Treinin, A., and Wilf, J., J. Am. Chem. Soc., 1972, vol. 94, p. 47.
Ziajka, J., Beer, F., and Warneck, P., Atmos. Environ., 1994, vol. 28, p. 2549.
Benkelberg, H.-J. and Warneck, P., J. Phys. Chem., 1995, vol. 99, p. 5214.
Chameides, W.L. and Davis, D.D., J. Geophys. Res., 1982, vol. 87, p. 4836.
Ermakov, A.N., Larin, I.K., Ugarov, A.A., and Purmal’, A.P., Kinet. Catal., 2006, vol. 47, no. 6, p. 849.
Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling, Jet Propulsion Laboratory Publication, Evaluation Number 12, 2006.
Mauldin, R.L., Mandronich, S., and Flocke, S.J., Geophys. Rev. Lett., 1997, vol. 24, p. 3033.
Berdnikov, V.M. and Bazhin, N.M., Zh. Fiz. Khim., 1970, vol. 44, p. 395.
Stanbury, D.M., Adv. Inorg. Chem., 1989, vol. 34, p. 69.
Knollenberg, R.G., in Clouds: Their Formation, Optical Properties and Effects, Hobbs, P.V. and Deepak, A., Eds., New York: Academic, 1981, p. 15.
Schwartz, S.E., in Chemistry of Multiphase Atmospheric Systems, NATO ASI Series, Jaeschke, W., Ed., Berlin: Springer, 1986, p. 415.
Herrmann, H., Ervens, B., Jacobi, H.-W., Wolke, R., Nowacki, P., and Zellner, R., J. Atmos. Chem., 2000, vol. 36, p. 231.
Sander, R., Compilations of Henry’s Law Constants for Inorganic and Organic Species of Potential Importance in Environmental Chemistry, Version 3, http://www.mpch-mainz.mpg.de/~sander/res/henry.html. Cited April 8, 1999.
Schwartz, S.E. and Freiberg, J.E., Atmos. Environ., 1981, vol. 15, p. 1129.
Exner, M., Herrmann, H., and Zellner, R., Ber. Bunsen-Ges. Phys. Chem., 1992, vol. 96, p. 470.
George, C., Ponche, J.L., Mirabel, P., Behnke, W., and Scheer, V., J. Phys. Chem., 1994, vol. 98, p. 8780.
Huie, R.E., Clifton, C.L., and Altstein, N., Radiat. Phys. Chem., 1989, vol. 33, no. 4, p. 361.
Betterton, E.A. and Hoffmann, M.R., J. Phys. Chem., 1988, vol. 92, no. 21, p. 5962.
Yermakov, A.N., Zhitomirsky, B.M., Poskrebyshev, G.A., and Sosurakov, D.M., J. Phys. Chem., 1993, vol. 97, no. 41, p. 10712.
Wine, P.H., Tang, Y., Thorn, R.P., and Wells, J.R., J. Geophys. Res. D: Atmos., 1989, vol. 94, no. 1, p. 1085.
Yermakov, A.N., Zhitomirsky, B.M., Poskrebyshev, G.A., and Stoliarov, S.I., J. Phys. Chem., 1995, vol. 99, no. 10, p. 3120.
Hoffman, M.R., Atmos. Environ., 1986, vol. 20, p. 1145.
Laj, P., Fuzzi, S., Lazzari, A., Ricci, L., and Orsi, G., Atmos. Environ., 1997, vol. 31, no. 16, p. 2503.
Laj, P., Fuzzi, S., Facchini, M.C., Lind, J.A., Orsi, G., Preiss, M., Maser, R., Jaeschke, W., Seyffer, E., Helaq, G., Acker, K., Wieprecht, W., Moller, D., Arends, B.G., Mols, G.G., Colvill, R.N., Galagher, M.W., Beswick, K.M., Hargreaves, K.J., Storetonwest, R.L., and Sutton, M.A., Atmos. Environ., 1997, vol. 31, no. 16, p. 2589.
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Original Russian Text © A.N. Yermakov, I.K. Larin, 2013, published in Kinetika i Kataliz, 2013, Vol. 54, No. 3, pp. 275–281.
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Yermakov, A.N., Larin, I.K. Nocturnal chemistry of sulfur dioxide in drops of tropospheric clouds. Kinet Catal 54, 263–269 (2013). https://doi.org/10.1134/S0023158413030038
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DOI: https://doi.org/10.1134/S0023158413030038