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Reactivity of thio (amino) derivatives of the ω-(4-hydroxyaryl)alkyl type in radical reactions

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Abstract

The enthalpies, activation energies, and rate constants of the reactions of thio (amino) alkylphenols of different structures were calculated and compared with those of the reactions of alkyl-substituted phenols, alkoxyl and alkyl radicals, hydroperoxides, and nitrogen dioxide, as well as the reactions of phenoxyl radicals with molecules of the substrate being oxidized. The calculation was performed by the intersecting parabolas method using O-H bond energy data for phenols. The correlation between the molecular structure of the thio (amino) alkylphenols and their reactivity in radical reactions is considered.

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Authors and Affiliations

  1. Siberian University of Consumer Cooperation, Novosibirsk, 630087, Russia

    E. I. Terakh

  2. Novosibirsk State Pedagogical University, Novosibirsk, 630090, Russia

    A. E. Prosenko

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  1. E. I. Terakh
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  2. A. E. Prosenko
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Correspondence to E. I. Terakh.

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Original Russian Text © E.I. Terakh, A.E. Prosenko, 2012, published in Kinetika i Kataliz, 2012, Vol. 53, No. 5, pp. 563–569.

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Terakh, E.I., Prosenko, A.E. Reactivity of thio (amino) derivatives of the ω-(4-hydroxyaryl)alkyl type in radical reactions. Kinet Catal 53, 537–542 (2012). https://doi.org/10.1134/S002315841205014X

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  • DOI: https://doi.org/10.1134/S002315841205014X

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