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Identification of nitrogen-containing species obtained by nitric oxide adsorption on the surface of model gold catalysts

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Abstract

Nitric oxide adsorption at 300–500 K on gold particles supported on an alumina film has been investigated for the first time by in situ X-ray photoelectron spectroscopy. Two nitrogen-containing adsorption species can form on the surface of gold particles. By test experiments on NO adsorption on the stepped face (533) of a gold single crystal, these species have been identified as adsorbed nitrogen atoms (which are detected throughout the temperature range examined) and a surface complex with N2O stoichiometry (which is stable in a narrow temperature range of 325–425 K).

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References

  1. Haruta, M., Chem. Phys., 2007, vol. 8, p. 1911.

    Article  CAS  Google Scholar 

  2. Lai, X., St. Clair, T.P., Valden, M., and Goodman, D.W., Prog. Surf. Sci., 1998, vol. 59, nos. 1–4, p. 25.

    Article  CAS  Google Scholar 

  3. Moroz, B.L., Pyrjaev, P.A., Zaikovskii, V.I., and Bukhtiyarov, V.I., Catal. Today, 2009, vol. 144, nos. 3–4, p. 292.

    Article  CAS  Google Scholar 

  4. Choudhary, T.V., Sivadinarayana, C., Goodman, D.W., et al., Catal. Lett., 2003, vol. 86, nos. 1–3, p. 1.

    Article  CAS  Google Scholar 

  5. Chusuei, C.C., Lai, X., Luo, K., and Goodman, D.W., Top. Catal., 2001, vol. 14, nos. 1–4, p. 71.

    Google Scholar 

  6. Schimpf, S., Lucas, M., Mohr, C., Roddemerck, U., Brückner, A., Radnik, J., Hofmeister, H., and Claus, P., Catal. Today, 2002, vol. 72, p. 63.

    Article  CAS  Google Scholar 

  7. Thompson, D.T., Gold Bull., 1999, vol. 32, no. 1, p. 32.

    Article  Google Scholar 

  8. Nieuwenhuys, B.E., Gluhoi, A.C., Rienks, E.D.L., Weststrate, C.J., and Vinod, C.P., Catal. Today, 2005, vol. 100, p. 49.

    Article  CAS  Google Scholar 

  9. Bukhtiyarov, V.I., Kaichev, V.V., and Prosvirin, I.P., Top. Catal., 2005, vol. 32, p. 3.

    Article  CAS  Google Scholar 

  10. Moulder, J.F., Stickle, W.F., Sobol, P.E., and Bomben, K.D., Handbook of X-Ray Photoelectron Spectroscopy, Eden Prairie, Minn.: PerkinElmer, 1992, p. 261.

    Google Scholar 

  11. Practical Surface Analysis by Auger and X-ray Photoelectron Spectroscopy, Briggs, D. and Seah, M.P., Eds., Chichester: Wiley, 1983.

    Google Scholar 

  12. Yeh, J.-J.. and Lindau, I., At. Data Nucl Data Tables, 1985, vol. 32, p. 1.

    Article  CAS  Google Scholar 

  13. Kulawik, M., Nilius, N., Rust, H.-P., and Freund, H.-J., Phys. Rev. Lett., 2003, vol. 91, no. 25, p. 256101–1.

    Article  CAS  Google Scholar 

  14. Vinod, C.P., Niemantsverdriet Hansa, J.W., and Nieuwenhuys, B.E., Appl. Catal., A, 2005, vol. 291, p. 93.

    Article  CAS  Google Scholar 

  15. Ueda, A. and Haruta, M., Gold Bull., 1999, vol. 32, no. 1, p. 3.

    Article  CAS  Google Scholar 

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Correspondence to A. V. Bukhtiyarov.

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Original Russian Text © A.V. Bukhtiyarov, A.V. Nartova, R.I. Kvon, 2011, published in Kinetika i Kataliz, 2011, Vol. 52, No. 5, pp. 772–777.

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Bukhtiyarov, A.V., Nartova, A.V. & Kvon, R.I. Identification of nitrogen-containing species obtained by nitric oxide adsorption on the surface of model gold catalysts. Kinet Catal 52, 756–760 (2011). https://doi.org/10.1134/S0023158411050041

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  • DOI: https://doi.org/10.1134/S0023158411050041

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