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On the chain nature of the third self-ignition limit of the detonating mixture

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Abstract

It is demonstrated by numerical simulation that neglect of branched chains at the third self-ignition limit of the detonating mixture is in conflict with actual observations.

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References

  1. Semenov, N.N., O nekotorykh problemakh khimicheskoi kinetiki i reaktsionnoi sposobnosti (Topics in Chemical Kinetics and Reactivity), Moscow: Akad. Nauk SSSR, 1958.

    Google Scholar 

  2. Lewis, B. and von Elbe, G., Combustion, Explosions and Flame in Gases, New York: Academic, 1987, p. 566.

    Google Scholar 

  3. Aleksandrov, E.N., Kuznetsov, N.M., and Kozlov, S.N., Fiz. Goreniya Vzryva, 2007, vol. 43, no. 5, p. 44.

    CAS  Google Scholar 

  4. Aleksandrov, E.N., Kuznetsov, N.M., and Kozlov, S.N., Dokl. Akad. Nauk, 2005, vol. 402, no. 4, p. 492 [Dokl. Phys. Chem. (Engl. Transl.), vol. 402, part 2, p. 85].

    Google Scholar 

  5. Azatyan, V.V., Baklanov, D.I., Bolod’yan, I.A, Vedeshkin, G.K., et al., Fiz. Goreniya Vzryva, 2008, vol. 44, no. 6, p. 130.

    CAS  Google Scholar 

  6. Azatyan, V.V. and Merzhanov, A.G., Khim. Fiz., 2008, vol. 27, no. 11, p. 93.

    CAS  Google Scholar 

  7. Rubtsov, N.M., Tsvetkov, G.I., and Chernysh, V.I., Zh. Fiz. Khim., 2009, vol. 83, no. 10, p. 1884 [Russ. J. Phys. Chem. (Engl. Transl.), vol. 83, no. 10, p. 1701].

    Google Scholar 

  8. Azatyan, V.V., Zh. Fiz. Khim., 2006, vol. 80, no. 1, p. 82 [Russ. J. Phys. Chem. (Engl. Transl.), vol. 80, no. 1, p. 72].

    Google Scholar 

  9. Azatyan, V.V., Kinet. Katal., 1996, vol. 37, no. 4, p. 512 [Kinet. Catal. (Engl. Transl.), vol. 37, no. 4, p. 480].

    Google Scholar 

  10. Azatyan, V.V., Kinet. Katal., 1999, vol. 40, no. 6, p. 818 [Kinet. Catal. (Engl. Transl.), vol. 40, no. 6, p. 741].

    Google Scholar 

  11. Frank-Kamenetskii, D.A., Diffuziya i teploperedacha v khimicheskoi kinetike (Diffusion and Heat Transfer in Chemical Kinetics), Moscow: Nauka, 1967.

    Google Scholar 

  12. Azatyan, V.V. and Merzhanov, A.G., in Khimicheskaya fizika na poroge XXI veka (Chemical Physics at the Turn of the 21st Century), Moscow: Nauka, 1996, p. 74.

    Google Scholar 

  13. Azatyan, V.V., Usp. Khim., 1999, vol. 69, no. 12, p. 22.

    Google Scholar 

  14. Poltorak, V.V. and Voevodskii, V.V., Zh. Fiz. Khim., 1950, vol. 24, no. 3, p. 299.

    CAS  Google Scholar 

  15. Willbourn, A.H. and Hinshelwood, C.N., Proc. R. Soc. London, Ser. A, 1946, vol. 185, no. 1003, p. 353.

    Article  CAS  Google Scholar 

  16. Semenov, N.N., Dokl. Akad. Nauk SSSR, 1951, vol. 81, no. 4, p. 645.

    CAS  Google Scholar 

  17. Brokaw, R.S., NASA Reports, Washington, DC, Dec. 1964.

  18. Park, Y.K. and Vlachos, D.G., J. Chem. Soc., Faraday Trans., 1998, vol. 94, p. 735.

    Article  CAS  Google Scholar 

  19. Azatyan, V.V., Bolod’yan, I.A., Navtsenya, V.Yu., and Shebeko, Yu.N., Zh. Fiz. Khim., 2002, vol. 76, no. 5, p. 775 [Russ. J. Phys. Chem. (Engl. Transl.), vol. 76, no. 5, p. 677].

    CAS  Google Scholar 

  20. Ivanova, A.N., Andrianova, Z.S., and Azatyan, V.V., Khim. Fiz., 1998, vol. 17, no. 8, p. 91.

    CAS  Google Scholar 

  21. Azatyan, V.V., Andrianova, Z.S., and Ivanova, A.N., Zh. Fiz. Khim., 2006, vol. 80, no. 7, p. 1194 [Russ. J. Phys. Chem. (Engl. Transl.), vol. 80, no. 7, p. 1044].

    Google Scholar 

  22. Azatyan, V.V., Aleksandrov, E.N., and Troshin, A.F., Kinet. Katal., 1975, vol. 16, p. 306.

    CAS  Google Scholar 

  23. Atkinson, R., Baulch, D.L., Cox, R.A., Hampson, R.F., Kerr, J.A., Rossi, M.J., and Troe, J., J. Phys. Chem. Ref. Data, 1997, vol. 26, p. 1329.

    CAS  Google Scholar 

  24. Baulch, D.L., Cobos, C.J., Cox, R.A., Esser, C., Frank, P., Just, Th., Kerr, J.A., Pilling, M.J., Troe, J., Walker, R.W., and Warnatz, J., J. Phys. Chem. Ref. Data, 1992, vol. 21, p. 411.

    Article  CAS  Google Scholar 

  25. Ryu, S-O., Hwang, S.M., and Rabinowitz, M.J., Chem. Phys. Lett., 1995, vol. 242, p. 279.

    Article  CAS  Google Scholar 

  26. Baulch, D.L., Bowman, C.T., Cobos, C.J., Cox, R.A., Just, Th., Kerr, J.A., Pilling, M.J., Stocker, D., Troe, J., Tsang, W., Walker, R.W., and Warnatz, J., J. Phys. Chem. Ref. Data, 2005, vol. 34, p. 566.

    Article  CAS  Google Scholar 

  27. Yang, H., Gardiner, W.C., Shin, K.S., and Fujii, N., Chem. Phys. Lett., 1994, vol. 231, p. 449.

    Article  CAS  Google Scholar 

  28. Hitch, B.D. and Senser, D.W., 26th Aerospace Sciences Meeting, Reno, Nev., 1988, AIAA-1988-732.

  29. Konnov, A.A., Khim. Fiz., 2004, vol. 23, p. 5.

    CAS  Google Scholar 

  30. Tablitsy fizicheskikh velichin: Spravochnik (Tables of Physical Quantities: A Handbook), Kikoin, E.K., Ed., Moscow: Atomizdat, 1976.

    Google Scholar 

  31. Baldwin, R.F. and Walker, R.W., J. Chem. Soc., Faraday Trans. 1, 1979, vol. 75, p. 140.

    Article  CAS  Google Scholar 

  32. Hinshelwood, C.N. and Thomson, H.W., Proc. R. Soc. London, Ser. A, 1928, vol. 118, p. 170.

    Article  CAS  Google Scholar 

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Correspondence to N. M. Rubtsov.

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Original Russian Text © N.M. Rubtsov, 2010, published in Kinetika i Kataliz, 2010, Vol. 51, No. 2, pp. 163–167.

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Rubtsov, N.M. On the chain nature of the third self-ignition limit of the detonating mixture. Kinet Catal 51, 149–153 (2010). https://doi.org/10.1134/S0023158410020011

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