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Catalytic Mo2C coatings for the water gas shift reaction: Electrosynthesis in molten salts

  • III International Conference “Catalysis: Fundamentals and Applications”
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Abstract

Electrosynthesis methods using molten salts are suggested for obtaining a new catalytic system based on the Mo2C/Mo composition for the water gas shift reaction. The coatings obtained by the discharge of the carbonate ion on a molybdenum substrate and by the simultaneous reduction of the electroactive species MoO 2−4 and CO 2−3 are catalytically more active than bulk Mo2C or the commercial catalyst Cu-ZnO-Al2O3 by one and three orders of magnitude, respectively.

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References

  1. Patt, J., Moon, D.-J., Phillips, C., and Thompson, L., Catal. Lett., 2000, vol. 65, p. 193.

    Article  CAS  Google Scholar 

  2. Moon, D.-J. and Ryu, J.W., Catal. Lett., 2004, vol. 92, p. 17.

    Article  CAS  Google Scholar 

  3. Lee, J.S., Oyama, S.T., and Boudart, M., J. Catal., 1987, vol. 106, p. 125.

    Article  CAS  Google Scholar 

  4. US Patent 6852303, 2005.

  5. US Patent 6623720, 2003.

  6. Kim, H.G., Lee, K.H., and Lee, J.S., Res. Chem. Intermed., 2000, vol. 26, p. 427.

    Article  CAS  Google Scholar 

  7. LaMont, D.C., Gilligan, A.J., Darujati, A.R.S., Chellappa, A.S., and Thomson, W.J., Appl. Catal., A, 2003, vol. 255, p. 239.

    Article  CAS  Google Scholar 

  8. Darujati, A.R.S., LaMont, D.C., and Thomson, W.J., Appl. Catal., A, 2003, vol. 253, p. 397.

    Article  CAS  Google Scholar 

  9. Zhu, Q., Zhang, B., Zhao, J., Ji, S., Yang, J., Wang, J., and Wang, H., J. Mol. Catal. A, 2004, vol. 213, p. 199.

    Article  CAS  Google Scholar 

  10. Nagai, M. and Matsuda, K., J. Catal., 2006, vol. 238, p. 489.

    Article  CAS  Google Scholar 

  11. Nagai, M., Zahidul, A.Md., and Matsuda, K., Appl. Catal., A, 2006, vol. 313, p. 137.

    Article  CAS  Google Scholar 

  12. Floquet, N., Bertrand, O., and Heizmann, J.J., Oxid. Met., 1992, vol. 37, p. 253.

    Article  CAS  Google Scholar 

  13. Mamantov, G., Molten Salts: Characterizations and Analysis, New York: Marcel Dekker, 1969.

    Google Scholar 

  14. Kuznetsov, S.A., Dubrovskiy, A.R., Rebrov, E.V., and Schouten, J.C., Z. Naturforsch., A: Phys. Sci., 2007, vol. 62, p. 647.

    CAS  Google Scholar 

  15. Ivanovskii, L.E. and Nekrasov, V.N., Gazy i ionnye rasplavy (Gases and Ionic Melts), Moscow: Nauka, 1979.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry, Kola Research Center, Russian Academy of Sciences, Apatity, Murmansk oblast, 184200, Russia

    A. R. Dubrovskii & S. A. Kuznetsov

  2. Chemical Reactor Engineering Group, Eindhoven University of Technology, Eindhoven, the Netherlands

    E. V. Rebrov & J. C. Schouten

Authors
  1. A. R. Dubrovskii
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  2. S. A. Kuznetsov
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  3. E. V. Rebrov
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  4. J. C. Schouten
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Corresponding author

Correspondence to S. A. Kuznetsov.

Additional information

Original Russian Text © A.R. Dubrovskii, S.A. Kuznetsov, E.V. Rebrov, J.C. Schouten, 2008, published in Kinetika i Kataliz, 2008, Vol. 49, No. 4, pp. 620–624.

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Dubrovskii, A.R., Kuznetsov, S.A., Rebrov, E.V. et al. Catalytic Mo2C coatings for the water gas shift reaction: Electrosynthesis in molten salts. Kinet Catal 49, 594–598 (2008). https://doi.org/10.1134/S0023158408040216

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  • DOI: https://doi.org/10.1134/S0023158408040216

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