Abstract
The results of studies on the state of platinum in alumina-platinum reforming catalysts performed at the Institute of Hydrocarbon Processing, Siberian Branch of the Russian Academy of Sciences, in the past 20 years are summarized. The main result is the determination of the important role of the nonmetallic states of platinum (Ptσ) in adsorption and catalysis. The main principles of the development of highly efficient catalysts and technologies for their manufacture are formulated. Data on the industrial applications of new reforming catalysts at seven commercial reforming plants under conditions of reforming gasoline production (about 3 million tons per year) with research octane numbers of 96–100 are given. The applicability of new catalysts to the combined conversion of C3–C4 and C5+ alkane mixtures into high-octane motor fuel components is demonstrated. The results of the development of three modifications of a new technology for the manufacture of environmentally safe high-octane gasoline with the selectivity of formation of the target product close to 100% are presented.
Similar content being viewed by others
References
Belyi, A.S., Smolikov, M.D., Fenelonov, V.B., Gavrilov, V.Yu., and Duplyakin, V.K., Kinet. Katal., 1986, vol. 27, no. 6, p. 1414.
Duplyakin, V.K., Belyi, A.S., Ostrovskii, N.M., Smolikov, M.D., Chalganov, E.M., and Nizovskii, A.I., Dokl. Akad. Nauk SSSR, 1989, vol. 305, no. 3, p. 648.
Belyi, A.S., Kiryanov, D.I., Smolikov, M.D., Zatolokina, E.V., Udras, I.E., and Duplyakin, V.K., Reac. Kinet. Catal. Lett., 1994, vol. 53, no. 1, p. 183.
Smolikov, M.D., Zaitsev, A.V., Khabibislamova, N.M., Belyi, A.S., Borovkov, V.Yu., Duplyakin, V.K., and Kazanskii, V.B., React. Kinet. Catal. Lett., 1994, vol. 53, no. 1, p. 169.
Smolikov, M.D., Zaitsev, A.V., Zatolokina, E.V., Belyi, A.S., Borovkov, V.Yu., Duplyakin, V.K., and Kazanskii, V.B., Kinet. Katal., 1992, vol. 33, no. 3, p. 625.
Belyi, A.S., Smolikov, M.D., Ostrovskii, N.M., Kolomytsev, Y.N., and Duplyakin, V.K., React. Kinet. Catal. Lett., 1988, vol. 37, no. 2, p. 457.
Duplyakin, V.K. and Belyi, A.S., 2nd Eur. Congr. on Catalysis, Maastricht, 1995, p. 725.
Belyi, A.S., Udras, I.E., Smolikov, M.D., and Kiryanov, D.I., 2nd Eur. Congr. on Catalysis, Maastricht, 1995, p. 714.
Belyi, A.S., Smolikov, M.D., Kir’yanov, D.I., Proskura, A.G., Udras, I.E., Duplyakin, V.K., Lugovskoi, A.I., Loginov, S.A., and Vashchenko, P.M., Katal. Promsti., 2003, no. 6, p. 3.
Belyi, A.S., Kinet. Katal., 2005, vol. 46, no. 5, p. 728 [Kinet. Catal. (Engl. Transl.), vol. 46, no. 5, p. 684].
Ostrovskii, N.M., Kinetika dezaktivatsii katalizatorov (Catalyst Deactivation Kinetics), Moscow: Nauka, 2001.
Belyi, A.S. and Lugovskoi, A.I., Khim. Prom-st., 1996, no. 3, p. 35.
Belyi, A.S., Doctoral (Chem.) Dissertation, Novosibirsk: Boreskov Inst. of Catalysis, 2002.
Ostrovskii, N.M. and Belyi, A.S., Khim. Prom-st., 1999, vol. 8, p. 522.
Smolikov, M.D., Belyi, A.S., Udras, I.E., and Kir’yanov, D.I., Ross. Khim. Zh., 2007, vol. 51, no. 4, p. 48.
Smirnova, I.E., Belyi, A.S., Smolikov, M.D., and Duplyakin, V.K., Kinet. Katal., 1990, vol. 31, no. 3, p. 687.
Belyi, A.S., Smolikov, M.D., Kir’yanov, D.I., and Udras, I.E., Ross. Khim. Zh., 2007, vol. 51, no. 4, p. 38.
Udras, I.E., Kiryanov, D.I., Smolikov, M.D., and Belyi, A.S., 4th Eur. East-West Conf. & Exhibition on Materials and Processes, St. Petersburg, 1993, vol. 1, p. 25.
Duplyakin, V.K., Doronin, V.P., Tsymbal, T.V., Al’t, L.Ya., and Belyi, A.S., Dokl. Akad. Nauk SSSR, 1985, vol. 281, no. 1, p. 89.
Belyi, A.S., Katal. Prom-sti., 2003, no. 2, p. 11.
Kir’yanov, D.I., Smolikov, M.D., Pashkov, V.V., Proskura, A.G., Zatolokina, E.V., Udras, I.E., and Belyi, A.S., Ross. Khim. Zh., 2007, vol. 51, no. 4, p. 60.
Belyi, A.S., III Int. Conf. on Catalysis: Fundamentals and Application, 2007, vol. 1, p. 121.
RF Patent 2144992, 2000.
RF Patent 2144056, 2000.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.S. Belyi, 2008, published in Kinetika i Kataliz, 2008, Vol. 49, No. 4, pp. 587–591.
Rights and permissions
About this article
Cite this article
Belyi, A.S. Design of reforming catalysts: Development of new technologies for the manufacture of motor fuels on this basis. Kinet Catal 49, 562–567 (2008). https://doi.org/10.1134/S0023158408040162
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0023158408040162