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The absolute value of the rate constant of the liquid-phase reaction SO −.5 + Fe(II)

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Abstract

An analytical method for monitoring the Fe2+ concentration during liquid-phase sulfite oxidation catalyzed by iron ions is described. The concentration conditions under which the Fe(III)/Fe(II) ratio is uniquely related to the rate constant of the reaction SO −.5 + Fe2+ are found by computer analysis. The experimental and calculated Fe(III)/Fe(II) ratio data are in agreement at \(k_{(SO_5^{ - \cdot } + Fe^{2 + } )} = 3.2 \times 10^6 1mol^{ - 1} s^{ - 1} \). This is one of the three rate constant values known from the literature, which differ by a factor greater than 70.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    O. A. Travina, Yu. N. Kozlov & A. P. Purmal

  2. Institute of Energy Problems of Chemical Physics, Chernogolovka Branch, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    A. N. Ermakov

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  1. O. A. Travina
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  2. A. N. Ermakov
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  3. Yu. N. Kozlov
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  4. A. P. Purmal
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Additional information

Original Russian Text © O.A. Travina, A.N. Ermakov, Yu.N. Kozlov, A.P. Purmal, 2006, published in Kinetika i Kataliz, 2006, Vol. 47, No. 3, pp. 347–352.

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Travina, O.A., Ermakov, A.N., Kozlov, Y.N. et al. The absolute value of the rate constant of the liquid-phase reaction SO −.5 + Fe(II). Kinet Catal 47, 341–346 (2006). https://doi.org/10.1134/S0023158406030037

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  • DOI: https://doi.org/10.1134/S0023158406030037

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