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L-Cysteine Nitrates

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Abstract

The formation of salts in the L-cysteine–HNO3–H2O system was studied yielding three representatives as single crystals: anhydrous L-cysteinium nitrate (L-CysH)NO3 (I) and two new salts (L-CysH⋯L-Cys)NO3 (II) and (L-CysH⋯L-Cys)NO3∙0.5H2O (III) with the dimeric (L-CysH⋯L-Cys) cation. (I), (II) and (III) crystallize in space groups P212121, P21 and I2, respectively. Dimeric cations in (II) and (III) were formed by very short O–H⋯O hydrogen bonds with R(O⋯O) distances of 2.440(2) Å and 2.4352(17) Å, respectively. Infrared and Raman spectra of (I–III) were registered and discussed in relation to crystal structures. Characteristics of dimeric cations are compared with those in the previously obtained compounds of L-CysH(L-CysH⋯L-Cys)F(F⋯HF), (L-CysH⋯L-Cys)Cl, (L-CysH⋯L-Cys)Br and (L-CysH⋯L-Cys)I·0.5H2O.

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Funding

This work was supported in part by a research grant matsc-3822 from the Armenian National Science and Education Fund (ANSEF) based in New York, USA.

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Authors and Affiliations

  1. Institute of Mineralogy and Crystallography, University of Vienna, Vienna, Austria

    G. Giester

  2. Institute of Applied Problems of Physics, National Academy of Sciences of Armenia, Yerevan, Armenia

    V. V. Ghazaryan & A. M. Petrosyan

  3. Max-Planck-Institut für Chemie, Mainz, Germany

    V. S. Minkov

  4. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    E. V. Boldyreva

  5. Novosibirsk State University, Novosibirsk, Russia

    E. V. Boldyreva

Authors
  1. G. Giester
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  2. V. V. Ghazaryan
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  3. V. S. Minkov
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  4. E. V. Boldyreva
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  5. A. M. Petrosyan
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Correspondence to E. V. Boldyreva or A. M. Petrosyan.

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Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 5, 111045.https://doi.org/10.26902/JSC_id111045

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Giester, G., Ghazaryan, V.V., Minkov, V.S. et al. L-Cysteine Nitrates. J Struct Chem 64, 917–931 (2023). https://doi.org/10.1134/S0022476623050104

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