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Honeycomb 3D Coordination Barium Polymer with 2-Furancarboxylic Acid Anions: Effect of Thermal Stability

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Abstract

A coordination polymer with the [Ba5(fur)10(H2O)4]n composition (1) is prepared by the reaction of barium(II) acetate and 2-furancarboxylic acid (pyrosmucus, Hfur) in an aqueous alcoholic solution. The XRD data show that 1 contains three symmetrically independent Ba2+ cations with different coordinations of fur– anions and different coordination numbers. All three oxygen atoms of the furoate anions are connected by chelate and bridging coordination bonds with cations to form a complex honeycomb 3D framework. The simultaneous thermal analysis (STA) shows that high thermal stability of 1 is due to the network of Ba2+ cations formed by alternating bi- and trinuclear linear fragments. Dehydration of coordinated water molecules from the composition of 1 does not cause the framework destruction up to 400 °C.

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Funding

The work was conducted out within the Russian Science Foundation project No. 22-13-00175.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    M. E. Nikiforova, I. A. Lutsenko, F. M. Dolgushin, A. V. Khoroshilov, M. A. Kiskin & I. L. Eremenko

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  1. M. E. Nikiforova
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  2. I. A. Lutsenko
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  3. F. M. Dolgushin
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  4. A. V. Khoroshilov
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Correspondence to M. E. Nikiforova.

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Russian Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 5, 110199.https://doi.org/10.26902/JSC_id110199

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Nikiforova, M.E., Lutsenko, I.A., Dolgushin, F.M. et al. Honeycomb 3D Coordination Barium Polymer with 2-Furancarboxylic Acid Anions: Effect of Thermal Stability. J Struct Chem 64, 884–894 (2023). https://doi.org/10.1134/S0022476623050074

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