Skip to main content
SpringerLink
Log in

A Two-Dimensional Barium(II) Coordination Polymer with Pyridinium-2,3-Dicarboxylate: Synthesis, Crystal Structure and Thermal Decomposition to Barium(II) Chloride Nanoparticles

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

A two-dimensional (2D) barium(II) coordination polymer [Ba(H2O)(µ-H2O)(µ-Cl)(µ-2,3-pyHdc)]n (1) (2,3-pyHdc = pyridinium-2,3-dicarboxylate), was prepared by reaction of barium(II) chloride dihydrate and pyridine-2,3-dicarboxylic acid in aqueous solution and characterized by elemental analysis, IR spectroscopy and TGA/DTA methods. The single-crystal X-ray structure analysis revealed that barium(II) ion in 1 has a distorted bicapped square-antiprismatic coordination geometry. The barium(II) ions are alternately bridged by the carboxylate O atoms only and by both carboxylate O atoms and water molecules, forming zig-zag chains of barium(II) ions extending along the [1 0 0] direction. All the barium(II) ions in these chains are also bridged by the chloride ions, resulting in the formation of an infinite 2D coordination network parallel to the (0 0 1) plane. Thermal decomposition of 1 in the presence of polyethylene glycol led to the formation of the BaCl2 nanoparticles. Powder X-ray diffraction (PXRD) and scanning electron microscopy (SEM) were used to characterize the structure and morphology of the prepared BaCl2 nanoparticles. The PXRD trace showed a formation of BaCl2 with an orthorhombic witherite structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. J. Gu, M. Wen, Y. Cai, Z. Shi, D.S. Nesterov, M.V. Kirillova, A.M. Kirillov, Inorg. Chem. 58, 5875 (2019)

    Article  CAS  Google Scholar 

  2. Y. Li, S.-H. Lu, R.-D. Zhao, Z.-X. Lu, X.-L. Liu, Y. Qin, S.-X. Yang, L.-Y. Zheng, Q.-E. Cao, Polym. Chem. 10, 2653 (2019)

    Article  CAS  Google Scholar 

  3. Y. Wang, X. Zhang, Y. Zhao, S. Zhang, S. Li, L. Jia, L. Du, Q. Zhao, Molecules 25, 382 (2020)

    Article  Google Scholar 

  4. S.A. Sotnik, R.A. Polunin, M.A. Kiskin, A.M. Kirillov, V.N. Dorofeeva, K.S. Gavrilenko, I.L. Eremenko, V.M. Novotortsev, S.V. Kolotilov, Inorg. Chem. 54, 5169 (2015)

    Article  CAS  Google Scholar 

  5. Z. Zhan, Y. Jia, D. Li, X. Zhang, M. Hu, Dalton Trans. 48, 15255 (2019)

    Article  CAS  Google Scholar 

  6. W. Gu, J. Gu, A.M. Kirillov, Crystals 10, 84 (2020)

    Article  CAS  Google Scholar 

  7. K. Biradha, A. Ramanan, J.J. Vittal, Cryst. Growth Des. 9, 2969 (2009)

    Article  CAS  Google Scholar 

  8. N. Yuan, Eur. J. Inorg. Chem. 4607 (2019)

  9. N. Zhao, Y. Li, J.Z. Gu, T.A. Fernandes, M.V. Kirillova, M.A. Kirillov, Molecules 24, 6 (2019)

    Article  Google Scholar 

  10. Y. Robin, K.M. Fromm, Coord. Chem. Rev. 250, 2127 (2006)

    Article  CAS  Google Scholar 

  11. Y. Song, X. Wang, S. Zhang, J. Wang, S. Gao, S. Chen, Z. Anorg, Allg. Chem. 642, 681 (2016)

    Article  CAS  Google Scholar 

  12. S. Taşcıoǧlu, A. Aydın, B. Yalçn, E. Kakı, Ö. Andac, O. Büyükgüngör, B. Koşar, Polyhedron 30, 2171 (2011)

    Article  Google Scholar 

  13. L.-L. Wen, Z.-D. Lu, X.-M. Ren, C.-Y. Duan, Q.-J. Meng, S. Gao, Cryst. Growth Des. 9, 227 (2009)

    Article  CAS  Google Scholar 

  14. Ž. Soldin, B.-M. Kukovec, D. Matković-Čalogović, Z. Popović, J. Inorg. Organomet. Polym. 28, 2080 (2018)

    Article  CAS  Google Scholar 

  15. M. Tabatabaee, A. Gholamighavamabad, E. Khabiri, M. Parvez, J. Inorg. Organomet. Polym. 21, 627 (2011)

    Article  CAS  Google Scholar 

  16. M. Tabatabaee, V. Razavimahmoudabadi, B.-M. Kukovec, M. Ghassemzadeh, B. Neumüller, J. Inorg. Organomet. Polym. 21, 450 (2011)

    Article  CAS  Google Scholar 

  17. R. Mohammadinasab, M. Tabatabaee, B.-M. Kukovec, H. Aghaie, Inorg. Chim. Acta 405, 368 (2013)

    Article  CAS  Google Scholar 

  18. M. Tabatabaee, R. Mohammadinasab, M. Aghaie, J. Inorg Organomet. Polym. 26, 127 (2016)

    Article  CAS  Google Scholar 

  19. M. Tabatabaee, M.R. Nateghi, R. Mohammadinasab, Monatsh. Chem. 146, 1641 (2015)

    Article  CAS  Google Scholar 

  20. M. Tabatabaee, S. Amjad, S. Tabatabaee, K. Molčanov, Synth. React. Inorg. Met-Org Nano-Met Chem. 44, 507 (2014)

    Article  CAS  Google Scholar 

  21. G. Ahadiat, M. Tabatabaee, K. Gholivand, K. Zare, M. Dušek, M.A. Kučeráková, Main Group Chem. 16(1), 7 (2017)

    Article  CAS  Google Scholar 

  22. M. Tabatabaee, B.-M. Kukovec, S. Amjad, M.R. Shishebor, Aust. J. Chem. 69, 1261 (2016)

    Article  CAS  Google Scholar 

  23. T.J. Meyer, J.A. McCleverty (eds.), Comprehensive Coordination Chemistry (Elsevier, New York, 2004), p. 22

    Google Scholar 

  24. F. Moghzi, J. Soleimannejad, J. Janczak, Nanotechnology 31, 245706 (2020)

    Article  CAS  Google Scholar 

  25. F. Moghzi, J. Soleimannejad, Ultrasonics Sonochem. 42, 193 (2018)

    Article  CAS  Google Scholar 

  26. S. Zhang, X.-N. Qu, G. Xie, Q. Wei, S.-P. Chen, J. Solid State Chem. 210, 36 (2014)

    Article  CAS  Google Scholar 

  27. G. Wu, F.J. Yin, H.-H. Li, L. Guo, J. Chem. Crystallogr. 42, 680 (2012)

    Article  CAS  Google Scholar 

  28. R.W.W. Hooft, COLLECT (Nonius BV, Delft, The Netherlands, 1998)

    Google Scholar 

  29. Z. Otwinowski, W. Minor, Methods in Enzymology, vol 276, Macromolecular Crystallography, Part A, ed. by C. W. Carter, R. M. Sweet (Academic Press, New York, 1997), p. 307

  30. R.H. Blessing, Acta Crystallogr. A 51, 33 (1995)

    Article  Google Scholar 

  31. G.M. Sheldrick, Acta Crystallogr. A 71, 3 (2015)

    Article  Google Scholar 

  32. G.M. Sheldrick, Acta Crystallogr. C 71, 3 (2015)

    Article  Google Scholar 

  33. C.F. Macrae, I. Sovago, S.J. Cottrell, P.T.A. Galek, P. McCabe, E. Pidcock, M. Platings, G.P. Shields, J.S. Stevens, M. Towler, P.A. Wood, J. Appl. Crystallogr. 53, 226 (2020)

    Article  CAS  Google Scholar 

  34. B. Cordero, V. Gomez, A.E. Platero-Prats, M. Reves, J. Echeverria, E. Cremades, F. Barragan, S. Alvarez, Dalton Trans. 2832 (2008).

  35. S. Alvarez, Dalton Trans. 42, 8617 (2013)

    Article  CAS  Google Scholar 

  36. C.R. Groom, I.J. Bruno, M.P. Lightfoot, S.C. Ward, Acta Crystallogr. B 72, 171 (2016)

    Article  CAS  Google Scholar 

  37. A. Lazarescu, S. Shova, J. Bartolome, P. Alonso, A. Arauzo, A.M. Balu, Y.A. Simonov, M. Gdaniec, C. Turta, G. Filoti, R. Luque, Dalton Trans. 40, 463 (2011)

    Article  CAS  Google Scholar 

  38. W. Starosta, J. Leciejewicz, J. Coord. Chem. 62, 1240 (2009)

    Article  CAS  Google Scholar 

  39. B. Barszcz, M. Hodorowicz, A. Jabłońska-Wawrzycka, J. Masternak, W. Nitek, K. Stadnicka, Polyhedron 29, 1191 (2010)

    Article  CAS  Google Scholar 

  40. B. Yusov, M.S. Grigor’ev, A.M. Fedoseev, Radiochemistry 55, 16 (2013)

    Article  CAS  Google Scholar 

  41. Y. Chang, Q. Shuai, Z. Pei, J. Coord. Chem. 66, 3137 (2013)

    Article  CAS  Google Scholar 

  42. W. Starosta, H. Ptasiewicz-Bąk, J. Leciejewicz, J. Coord. Chem. 56, 33 (2003)

    Article  CAS  Google Scholar 

  43. M.A.S. Goher, R.-J. Wang, T.C.W. Mak, J. Crystallogr. Spectrosc. Res. 20, 245 (1990)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This research was supported by the Islamic Azad University, Yazd Branch, Iran and University of Split, Croatia.

Supplementary material

CCDC 994304 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif (or from the Cambridge Crystallographic Data Centre (CCDC), 12 Union Road, Cambridge CB2 1EZ, UK; fax:+44(0)1223-336033; email: deposit@ccdc.cam.ac.uk).

Author information

Authors and Affiliations

  1. Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran

    Zahra Mohammadi, Masoumeh Tabatabaee & Razieh Mohebat

  2. Department of Physical Chemistry, Faculty of Chemistry and Technology, University of Split, Ruđera Boškovića 35, 21000, Split, Croatia

    Boris-Marko Kukovec

Authors
  1. Zahra Mohammadi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Masoumeh Tabatabaee
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Razieh Mohebat
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Boris-Marko Kukovec
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Masoumeh Tabatabaee or Boris-Marko Kukovec.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 462 kb)

Supplementary file2 (PDF 182 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mohammadi, Z., Tabatabaee, M., Mohebat, R. et al. A Two-Dimensional Barium(II) Coordination Polymer with Pyridinium-2,3-Dicarboxylate: Synthesis, Crystal Structure and Thermal Decomposition to Barium(II) Chloride Nanoparticles. J Inorg Organomet Polym 30, 5209–5216 (2020). https://doi.org/10.1007/s10904-020-01670-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-020-01670-y

Keywords

Search

Navigation