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STABILITY AND REPRODUCIBILITY OF THE DIMERIC MOTIF IN THE CRYSTALS OF THIOETHERS OF 3-BROMO-5-HYDROXY-1- (4-METHYLBENZYL)-1,5-DIHYDRO-2H-PYRROL-2-ONES

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Abstract

We confirm our previously formulated rule about the possibility of a spontaneous resolution of enantiomers of a series of 5-hydroxy-3-pyrrolin-2-one thioderivatives. Crystal packings of three racemic compounds are compared. A supramolecular associate of the same type (a hydrogen-bonded dimer) is found, which is differently packed in the 3D structure of the crystals.

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Funding

Physicochemical studies were carried out in the Multi-Access Spectral Analytical Center of the Kazan Scientific Center, Russian Academy of Sciences and supported by the State Assignment of the Kazan Scientific Center, Russian Academy of Sciences.

The synthesis of the key compounds was supported by the Kazan Federal University Strategic Academic Leadership Program (Priority-2030).

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia

    D. P. Gerasimova, D. V. Zakharychev, A. F. Saifina & O. A. Lodochnikova

  2. Butlerov Chemical Institute, Kazan (Volga region) Federal University, Kazan, Russia

    R. G. Faizova & A. R. Kurbangalieva

Authors
  1. D. P. Gerasimova
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  2. R. G. Faizova
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  3. D. V. Zakharychev
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  4. A. F. Saifina
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  5. A. R. Kurbangalieva
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  6. O. A. Lodochnikova
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Corresponding author

Correspondence to D. P. Gerasimova.

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The authors declare that they have no conflicts of interests.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 10, 99529.https://doi.org/10.26902/JSC_id99529

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Gerasimova, D.P., Faizova, R.G., Zakharychev, D.V. et al. STABILITY AND REPRODUCIBILITY OF THE DIMERIC MOTIF IN THE CRYSTALS OF THIOETHERS OF 3-BROMO-5-HYDROXY-1- (4-METHYLBENZYL)-1,5-DIHYDRO-2H-PYRROL-2-ONES. J Struct Chem 63, 1616–1628 (2022). https://doi.org/10.1134/S0022476622100080

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