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SYNTHESIS AND STRUCTURE OF PALLADACYCLOPENTADIENYL COMPLEX WITH ACENAPHTHENE-1,2-DIIMINE LIGAND

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Abstract

The organometallic complex [Pd(dpp-bian)(C4(COOMe)4)]·(C2H5)2O (1·(C2H5)2O) is obtained by the interaction of [Pd2(dba)3] (dba = dibenzylideneacetone) with dimethyl ether of acetylenedicarboxylic acid and 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian) in the 1:4:2 molar ratio. During the oxidative addition reaction the 1,2,3,4-tetrakis(methoxycarbonyl)buta-1,3-dienyl dianion is formed from two molecules of dimethyl ether of acetylenedicarboxylic acid. This dianion is coordinated to palladium(II) via 1 and 4 carbon atoms with the formation of the palladacyclopentadienyl moiety. The crystal structure is determined by the single crystal X-ray diffraction analysis. The 1·(C2H5)2O compound crystallizes in the orthorhombic crystal system (Pbca) with unit cell parameters a = 16.9069(3) Å, b = 23.5618(6) Å, c = 23.8902(7) Å, V = 9516.83(40) Å3. Each palladium atom has an almost square planar environment composed of two dpp-bian nitrogen atoms and two carbon atoms of the (C4(COOMe)4)2– anion. The cyclic voltammogram of 1 in acetonitrile reveals irreversible oxidation at Ea = 1.43 V, reversible reduction at E1/2 = 0.62 V, and irreversible reduction at Eb = 1.52 V. The electronic structure of complex 1 is studied within the density functional theory.

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Funding

The work was supported by RFBR (grant No. 21-13-00092) and the Ministry of Sciences and Higher Education of the Russian Federation (project No. 121031700315-2).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    N. F. Romashev, I. V. Bakaev, M. N. Sokolov & A. L. Gushchin

  2. Novosibirsk State University, Novosibirsk, Russia

    I. V. Bakaev & V. I. Komlyagina

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  1. N. F. Romashev
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Correspondence to A. L. Gushchin.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 8, 96304.https://doi.org/10.26902/JSC_id96304

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Romashev, N.F., Bakaev, I.V., Komlyagina, V.I. et al. SYNTHESIS AND STRUCTURE OF PALLADACYCLOPENTADIENYL COMPLEX WITH ACENAPHTHENE-1,2-DIIMINE LIGAND. J Struct Chem 63, 1304–1312 (2022). https://doi.org/10.1134/S002247662208011X

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