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AN INVESTIGATION INTO THE IMPACT OF INTRODUCED THIOCYANATE ANIONS ON THE TRINUCLEAR Co(II) SALAMO-BASED COMPLEX

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Abstract

The reaction of Co(OAc)2·4H2O with multisite coordinated salamo-based ligand H2L containning six coordinating sites in presence of co-ligand NCS– anions afforded successfully a trinuclear Co(II) complex [Co3(L)2(NCS)2]. The trinuclear Co(II) complex has been characterized by elemental analyses, UV-Vis, Fourier transform infrared spectroscopic methods and DFT calculation. In addition, the structure of the Co(II) complex has been confirmed by single crystal X-ray crystallography. X-ray crystal structure analysis of the Co(II) complex revealed that the Co(II) complex consists of three Co(II) atoms coordinated by two fully deprotonated ligand (L)2– units and co-ligand NCS– anions. The close surveillance of the crystal structure of the Co(II) complex discloses some notable non-covalent interactions like H-bonding, C-H⋯π and π⋯π. The luminescent property of the Co(II) complex has been studied in methanol solution. Apart from, as a complementary revelation, intermolecular interactions with respect to percentages of hydrogen bondings in the X-ray crystal structure of the trinuclear Co(II) complex was quantified by analyses of Hirshfeld surfaces and fingerprint plots.

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This work was supported by the National Natural Science Foundation of China (21761018), which is gratefully acknowledged.

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  1. School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University, People’s Republic of China

    K.-F. Xie, Y. Huang, S.-Z. Li, L.-L. Li & W.-K. Dong

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  1. K.-F. Xie
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  2. Y. Huang
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Correspondence to W.-K. Dong.

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Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 8, 96112.https://doi.org/10.26902/JSC_id96112

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Xie, KF., Huang, Y., Li, SZ. et al. AN INVESTIGATION INTO THE IMPACT OF INTRODUCED THIOCYANATE ANIONS ON THE TRINUCLEAR Co(II) SALAMO-BASED COMPLEX. J Struct Chem 63, 1262–1273 (2022). https://doi.org/10.1134/S0022476622080078

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