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STUDY OF Pt/Ce-Mn-Ox CATALYSTS FOR THE LOW-TEMPERATURE CO OXIDATION REACTION

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Abstract

The possibility to obtain low-temperature active platinum-based catalysts is investigated. Catalysts of the composition Pt/Ce1–xMnxO2–δ are synthesized in two steps: firstly, Ce1–xMnxO2–δ carriers with different manganese concentrations (10-30 at.%) are obtained by co-precipitation, then final catalysts are prepared by impregnating with platinum nitrate. The introduction of manganese into the carrier composition is found to decrease the platinum load to the required one for anomalous low-temperature СО oxidation at Т < 0 °C.

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Funding

The work was supported by RFBR and the Government of the Novosibirsk Oblast’ within research project No. 20-43-540009 and also with partial support of the Ministry of Science and Higher Education of the Russian Federation within State Assignment for the Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences (project АААА-А21-121011390053-4).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. I. Stadnichenko, A. A. Simanenko, E. M. Slavinskaya, E. A. Fedorova, O. A. Stonkus, A. V. Romanenko & A. I. Boronin

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  1. A. I. Stadnichenko
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  2. A. A. Simanenko
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  3. E. M. Slavinskaya
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  4. E. A. Fedorova
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  5. O. A. Stonkus
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Correspondence to A. I. Stadnichenko.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 8, 95129.https://doi.org/10.26902/JSC_id95129

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Stadnichenko, A.I., Simanenko, A.A., Slavinskaya, E.M. et al. STUDY OF Pt/Ce-Mn-Ox CATALYSTS FOR THE LOW-TEMPERATURE CO OXIDATION REACTION. J Struct Chem 63, 1199–1214 (2022). https://doi.org/10.1134/S0022476622080017

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