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STRUCTURAL AND CHEMICAL FEATURES OF CHALCOGENIDES OF EARLY TRANSITION METALS

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Abstract

This review is aimed at the generalization of structures, electronic and functional properties of early transition metal (Groups 4-7) chalcogenides (ETMCs) (M = Ti, Zr, Hf, V, Nb, Ta, Mo, W, Re). The structures of various chalcogenides, the preparation of nanomaterials based on them, the effect of the electronic properties of metals and chalcogens on the structural and functional features of metal chalcogenides are considered. The nature of polymerization in ETMCs and redox properties of chalcogens are discussed.

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation (CITIS 121031700321-3) and the Russian Science Foundation (project No. 21-13-00274, https://rscf.ru/project/21-13-00274/).

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  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. B. Artemkina, E. D. Grayfer, M. N. Ivanova, A. Yu. Ledneva, A. A. Poltarak, P. A. Poltarak, S. S. Yarovoi, S. G. Kozlova & V. E. Fedorov

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  1. S. B. Artemkina
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  3. M. N. Ivanova
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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 7, 96292.https://doi.org/10.26902/JSC_id96292

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Artemkina, S.B., Grayfer, E.D., Ivanova, M.N. et al. STRUCTURAL AND CHEMICAL FEATURES OF CHALCOGENIDES OF EARLY TRANSITION METALS. J Struct Chem 63, 1079–1100 (2022). https://doi.org/10.1134/S002247662207006X

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