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PREPARATION AND CRYSTAL STRUCTURE OF THE TANTALUM BROMIDE CLUSTER COMPLEX [Li(diglyme)2]2[Ta6Br18]

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Abstract

Extracting the reaction product of Ta, Br2, and LiBr (720 °C, 48 h, mole ratio 1.5:1.75:1.0) with diglyme yields crystals of complex [Li(diglyme)2]2[Ta6Br18] whose structure is determined by XRD.

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Funding

This work was funded by the Ministry of Science and Higher Education of the Russian Federation, project No. 121031700313-8 (sample preparation, determination of the chemical composition and the structure of 1) and by RFBR, project No. 20-33-90010 (development and optimization of synthesis methods for compound 1).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    M. V. Shamshurin, P. A. Abramov, M. A. Mikhaylov & M. N. Sokolov

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  1. M. V. Shamshurin
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  2. P. A. Abramov
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  3. M. A. Mikhaylov
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  4. M. N. Sokolov
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Corresponding author

Correspondence to M. N. Sokolov.

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The authors declare that they have no conflict of interests.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 1, pp. 42-47.https://doi.org/10.26902/JSC_id85863

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Shamshurin, M.V., Abramov, P.A., Mikhaylov, M.A. et al. PREPARATION AND CRYSTAL STRUCTURE OF THE TANTALUM BROMIDE CLUSTER COMPLEX [Li(diglyme)2]2[Ta6Br18]. J Struct Chem 63, 81–86 (2022). https://doi.org/10.1134/S0022476622010097

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  • DOI: https://doi.org/10.1134/S0022476622010097

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