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PROPIOLATE CLUSTER COMPLEXES (Bu4N)2[Mo6X8(OOC–C≡CH)6] (X = Br, I)

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Abstract

Two new cluster complexes (Bu4N)2[Mo6X8(OOC–C≡CH)6] (1) (X = Br) and (2) (X = I) are synthesized by the reaction of (Bu4N)2[Mo6X8(OOCCH3)6] (X = Br, I) with HOOC–C≡CH propiolic acid, their crystal structures are determined, and the luminescent properties are studied for powder samples at different temperatures. According to X-ray crystallographic data, molybdenum atoms are monodentately coordinated by oxygen atoms of the carboxyl group at Mo–O distances of 2.108(2)-2.121(16) Å. The propiolate complexes are characterized by electrospray mass spectrometry, 1Н and 13С NMR, elemental analysis, and IR spectroscopy.

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation, project No. 121031700313-8 (study of the electrochemical properties of new cluster complexes 1 and 2, preparation of samples, and determination of the chemical composition and structures of 1 and 2), RFBR grant No. 20-03-00410 (search and optimization of synthesis methods for new cluster compound 1 and 2), and Russian Science Foundation grant No. 19-73-20196 (study of luminescent properties of new cluster complexes 1 and 2).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    M. A. Mikhailov, A. S. Berezin, T. S. Sukhikh, D. G. Sheven’, A. L. Gushchin & M. N. Sokolov

  2. Novosibirsk State University, Novosibirsk, Russia

    M. N. Sokolov

  3. Kazan (Volga region) Federal University, Kazan, Russia

    M. N. Sokolov

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  1. M. A. Mikhailov
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  2. A. S. Berezin
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  3. T. S. Sukhikh
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  4. D. G. Sheven’
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  5. A. L. Gushchin
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  6. M. N. Sokolov
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Correspondence to M. A. Mikhailov.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 12, pp. 2016-2027.https://doi.org/10.26902/JSC_id84479

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Mikhailov, M.A., Berezin, A.S., Sukhikh, T.S. et al. PROPIOLATE CLUSTER COMPLEXES (Bu4N)2[Mo6X8(OOC–C≡CH)6] (X = Br, I). J Struct Chem 62, 1896–1906 (2021). https://doi.org/10.1134/S002247662112009X

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