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1,2,4-TRIAZOLATE CLUSTER COMPLEXES (Bu4N)2[Mo6X8(N3C2H2)6] (X = Br, I)

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Abstract

Two new luminescent cluster complexes (Bu4N)2[Mo6X8(N3C2H2)6]·n(H2O) (1) (X = Br, n = 4) and (2) (X = I, n = 5) are obtained by the reaction of (Bu4N)2[Mo6X8(OOCCH3)6] (X = Br, I) with 1-trimethylsilyl-1,2,4-triazole Me3Si–N3C2H2. Their crystal structures are determined and the luminescent properties of powder samples are studied. According to single crystal X-ray diffraction data, molybdenum atoms are monodentate coordinated by N1 atoms of triazolate ligands at Mo–N distances of 2.154(9)-2.185(9) Å (1) and 2.158(13)-2.21(13) Å (2). The complexes are characterized by electrospray mass spectrometry, proton magnetic resonance, elemental analysis, and IR spectroscopy data.

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700313-8 for the study of the luminescent properties of new cluster complexes 1 and 2, determination of the chemical compositions and structures of 1 and 2) and RFBR (grant No. 20-03-00410 for the synthesis of 1 and 2).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    M. A. Mikhaylov, A. S. Berezin, T. S. Sukhikh, D. G. Sheven’, N. B. Kompankov & M. N. Sokolov

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  1. M. A. Mikhaylov
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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 12, 103869.https://doi.org/10.26902/JSC_id103869

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Mikhaylov, M.A., Berezin, A.S., Sukhikh, T.S. et al. 1,2,4-TRIAZOLATE CLUSTER COMPLEXES (Bu4N)2[Mo6X8(N3C2H2)6] (X = Br, I). J Struct Chem 63, 2101–2112 (2022). https://doi.org/10.1134/S0022476622120216

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