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SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF HETEROLEPTIC Cu(I) DITHIOCARBAMATE COMPLEX CONTAINING DIPHENYL PHOSPHINOFERROCENE (dppf)

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Abstract

A new copper(I) heteroleptic pyridyl functionalized dithiocarbamate(dtc) complex, [Cu(L)2dppf]·2H2O·MeOH, (1) (where L = N-benzyl-N-methylpyridyldtc and dppf = = diphenyl phosphinoferrocene), has been synthesized from the reaction of [Cu2(μ-Br)2(k2-P,P-dppf)2] and dithiocarbamate ligand (L). The synthesized complex has been characterized by elemental analysis, spectroscopy techniques (IR, 1H, 13C, 31P NMR, and UV-Vis), and single-crystal X-ray crystallography. In this heteroleptic complex, the Cu atom forms distorted tetrahedral coordination geometry. The supramolecular architecture in the complex has been sustained in the solid phase by, C–H⋯O and C–H⋯π (chelate = CuS2C) interactions. The emission spectrum of the complex has been studied in DCM solution. The charge-transfer excited state is quenched due to intramolecular energy transfer from the {Cu(S,S)(P,P)} moiety to the ferrocene therefore dppf-based complex shows no detectable emission at room temperature. This complex is weakly conducting and exhibit semiconductor behavior at room temperature.

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Authors and Affiliations

  1. Department of Chemistry, B.S.A. College, Mathura, Republic of India

    V. Kumar

  2. Department of Chemistry, Guru Ghasidas Vishwavidyalaya, Bilaspur, Republic of India

    S. Singh

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 11, pp. 1835-1843.https://doi.org/10.26902/JSC_id82655

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Kumar, V., Singh, S. SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF HETEROLEPTIC Cu(I) DITHIOCARBAMATE COMPLEX CONTAINING DIPHENYL PHOSPHINOFERROCENE (dppf). J Struct Chem 62, 1723–1731 (2021). https://doi.org/10.1134/S0022476621110081

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