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SPATIAL STRUCTURE OF MONO AND BIS AMIDE-SUBSTITUTED p-TERT-BUTYL-THIACALIX[4]ARENES IN THE CRYSTAL PHASE

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Abstract

Molecular and crystal structures of four lower rim substituted tert-butyl-thiacalix[4]arenes are studied. It is shown that the cone conformation of the macrocycle can be regulated by the number, type, attachment point, and the size of substituents at the lower rim. Isomers with the 1,3-alternate macrocycle conformation are most preferable due to large substituents.

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Funding

The work was funded by a State Assignment for the FRC KSC RAS.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Subdivision of the Federal State Budgetary Institution of Science “Kazan Scientific Center of Russian Academy of Sciences”, Kazan, Russia

    I. A. Litvinov, D. A. Islamov, O. A. Ovsyannikov & S. E. Solovieva

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  1. I. A. Litvinov
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  2. D. A. Islamov
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  3. O. A. Ovsyannikov
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  4. S. E. Solovieva
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Correspondence to I. A. Litvinov.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 9, pp. 1529-1538.https://doi.org/10.26902/JSC_id85811

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Litvinov, I.A., Islamov, D.A., Ovsyannikov, O.A. et al. SPATIAL STRUCTURE OF MONO AND BIS AMIDE-SUBSTITUTED p-TERT-BUTYL-THIACALIX[4]ARENES IN THE CRYSTAL PHASE. J Struct Chem 62, 1432–1440 (2021). https://doi.org/10.1134/S0022476621090122

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  • DOI: https://doi.org/10.1134/S0022476621090122

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