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RACEMIC TWINNING OF 7-CHLORINE-2,3,4a,6- TETRAHYDROFURO[2,3-b][1,4]OXATHIIN-6-ONE CRYSTALS

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Abstract

An unusual type of rac-7-chlorine-2,3,4a,6-tetrahydrofuro[2,3-b][1,4]oxathiin-6-one crystallization is reported. This compound crystallizes in the form of lamellar conglomerates where each single crystal is not optically pure but is only enantiomerically enriched by one optical antipode and displays optical rotation.

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Funding

The work was funded by the State Assignment for FRC Kazan Scientific Center of RAS.

The synthesis of the main compound was funded by the Ministry of Education and Science of the Russian Federation (grant for the Kazan Federal University within the State Assignment in the field of scientific activity No.0671-2020-0063).

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Subdivision of the Federal State Budgetary Institution of Science “Kazan Scientific Center of Russian Academy of Sciences”, Kazan, Russia

    D. P. Gerasimova, O. A. Lodochnikova & I. A. Litvinov

  2. Kazan (Volga region) Federal University, Alexander Butlerov Institute of Chemistry, Kazan, Russia

    A. R. Kurbangalieva

Authors
  1. D. P. Gerasimova
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  2. O. A. Lodochnikova
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  3. A. R. Kurbangalieva
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  4. I. A. Litvinov
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Corresponding author

Correspondence to D. P. Gerasimova.

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The authors declare that they have no conflict of interests.

Additional information

Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 9, pp. 1522-1528.https://doi.org/10.26902/JSC_id79938

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Gerasimova, D.P., Lodochnikova, O.A., Kurbangalieva, A.R. et al. RACEMIC TWINNING OF 7-CHLORINE-2,3,4a,6- TETRAHYDROFURO[2,3-b][1,4]OXATHIIN-6-ONE CRYSTALS. J Struct Chem 62, 1425–1431 (2021). https://doi.org/10.1134/S0022476621090110

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  • DOI: https://doi.org/10.1134/S0022476621090110

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