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TWO INTERPENETRATING COBALT COORDINATION POLYMERS CONSTRUCTED BY DICARBOXYLATE AND V-SHAPED N-DONOR LIGANDS

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Abstract

Two novel cobalt coordination polymers {[L1Co(ipa)]·0.25(DMF)}n (1) and {[L2Co(cis-1,3-chdc)]·3(H2O)}n (2) (L1 = bis(4-(1H-benzo[d]imidazol-1-yl)phenyl)methanone, L2 = bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2ipa = isophthalic acid, H2(cis-1,3-chdc) = cis-1,3-cyclohexanedicarboxylic acid) are prepared under solvothermal conditions. These complexes are characterized by elemental analyses, IR spectroscopy, and X-ray crystallography. Complex 1 presents a 4-fold 3D network with a diamond net, while complex 2 shows a 2-fold 2D network with a square-grid net.

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Funding

This research was supported by the Young Teacher Starting-up Research of Yuncheng University (YQ-2019022), the Priority Academic Program of Applied Chemistry (XK-2019057), and Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province (2019L0857).

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Authors and Affiliations

  1. Department of Applied Chemistry, Yuncheng University, Yuncheng, People’s Republic of China

    G. -F. Wang & S. -W. Sun

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  1. G. -F. Wang
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  2. S. -W. Sun
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Correspondence to G. -F. Wang.

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Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 8, pp. 1351-1356.https://doi.org/10.26902/JSC_id78492

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Wang, G.F., Sun, S.W. TWO INTERPENETRATING COBALT COORDINATION POLYMERS CONSTRUCTED BY DICARBOXYLATE AND V-SHAPED N-DONOR LIGANDS. J Struct Chem 62, 1263–1269 (2021). https://doi.org/10.1134/S0022476621080138

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