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STRUCTURE AND CATALYTIC PROPERTIES OF (ACETYLACETONATO-κ2O,O′)BIS(TRI(2-FURYL)PHOSPHINE) PALLADIUM(II) TETRAFLUOROBORATE

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Abstract

Reaction of Pd(acac)2 with BF3·OEt2 in the presence of tri(2-furyl)phosphine in toluene yields complex [Pd(acac)(TFP)2]BF4 (I) (TFP is tri(2-furyl)phosphine) whose structure is determined by XRD. The crystal structure of I contains short H⋯F contacts. The energies of these contacts are studied using DFT quantum chemical methods. Coordination complex I in combination with BF3·OEt2 in appropriate concentrations and solvents demonstrates catalytic activity in the reaction of morpholine allylic alkylation characterized by the catalyst turnover number from 198 mol to 268 mol of 4-allylmorpholine per mole of palladium and an integral selectivity to the main product of 88-99%.

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Funding

The study was supported by the Russian Science Foundation (project No. 19-73-00046).

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Authors and Affiliations

  1. Irkutsk State University, Irkutsk, Russia

    M. V. Bykov, Z. D. Abramov, T. S. Orlov, M. V. Pakhomova & D. S. Suslov

  2. Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

    T. N. Borodina & V. I. Smirnov

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 8, pp. 1305-1316.https://doi.org/10.26902/JSC_id81367

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Bykov, M.V., Abramov, Z.D., Orlov, T.S. et al. STRUCTURE AND CATALYTIC PROPERTIES OF (ACETYLACETONATO-κ2O,O′)BIS(TRI(2-FURYL)PHOSPHINE) PALLADIUM(II) TETRAFLUOROBORATE. J Struct Chem 62, 1218–1228 (2021). https://doi.org/10.1134/S0022476621080072

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