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A COMPARATIVE STUDY OF THE DEPOSITION OF NANOSCALE Au–S INTERMEDIATES FROM AQUEOUS SOLUTIONS ON CuO, TiO2, AND α-Fe2O3 SURFACES

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Abstract

Products of the interaction between dispersed copper(II), iron(III) (hematite), and titanium(IV) (rutile) oxides and aqueous solutions containing liquid prenucleation intermediates formed in the reaction of HAuCl4 and sodium sulfide with the initial 1:3 molar ratio of the reagents are studied by X-ray photoelectron spectroscopy, Cu L-, Fe L-, Ti L-, O K X-ray absorption near edge structure spectroscopy in combination with transmission electron microscopy. It is found that in comparison with treatment of supports with a HAuCl4 solution, the amount of deposited gold significantly increases in the presence of sulfide ions. Gold nanoparticles covered with adsorbed sulfur form on three studied oxides as a decomposition product of strongly disordered gold(I) sulfide. On copper oxide, discernibly larger gold nanoparticles (with a diameter of about 10 nm against 3-5 nm on hematite and rutile) are observed. The surface of the support is sulfidized.

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Funding

The study was supported by RFBR, the Government of Krasnoyarsk region, and the Krasnoyarsk Regional Science Foundation within scientific project 17-45-240759 r_a.: “Study of the Interaction of Aqueous Solutions of Nano- and Submicronic Particles of Gold, Platinum, and Palladium Sulfides with Sulfide and Oxide Minerals”.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russia

    M. N. Likhatskii, A. A. Karacharov, A. S. Romanchenko & Yu. L. Mikhlin

  2. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. I. Zaikovskii

  3. Novosibirsk State University, Novosibirsk, Russia

    V. I. Zaikovskii

Authors
  1. M. N. Likhatskii
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  2. A. A. Karacharov
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  3. A. S. Romanchenko
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  4. V. I. Zaikovskii
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  5. Yu. L. Mikhlin
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Correspondence to M. N. Likhatskii.

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The authors declare that they have no conflict of interests.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 4, pp. 655-663.https://doi.org/10.26902/JSC_id71157

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Likhatskii, M.N., Karacharov, A.A., Romanchenko, A.S. et al. A COMPARATIVE STUDY OF THE DEPOSITION OF NANOSCALE Au–S INTERMEDIATES FROM AQUEOUS SOLUTIONS ON CuO, TiO2, AND α-Fe2O3 SURFACES. J Struct Chem 62, 613–621 (2021). https://doi.org/10.1134/S0022476621040132

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  • DOI: https://doi.org/10.1134/S0022476621040132

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