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STRUCTURE AND PROPERTIES OF THE MIXED-LIGAND COMPLEX COMPOUND OF GADOLINIUM STEARATE WITH BENZOYLTRIFLUOROACETONE

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Abstract

By IR spectroscopy and the elemental analysis the composition of the synthesized mixed-ligand complex compound of gadolinium stearate with benzoyltrifluoroacetone (GdSt2BTFA·2H2O) is determined. By optical microscopy and powder X-ray diffraction it is found that the compound is a well-crystallized powder. EPR spectra of the gadolinium stearate powder with benzoyltrifluoroacetone are measured in the range 103-293 K. The zero field splitting parameter is D = 1329.6 MHz. By DFT calculations it is established that the most probable symmetry point group of the synthesized mixed-ligand complex of gadolinium stearate with benzoyltrifluoroacetone is D2d. The Curie temperature θ = 13.52 K and the Curie constant С = 2.42 m3·K/kg are determined and the effective magnetic moment μeff = 7.93 is calculated in the entire temperature range studied for the gadolinium stearate benzoyltrifluoroacetone powder.

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REFERENCES

  1. V. T. Panyushkin, Yu. A. Afanasyev, and E. I. Khanaev. Lantanoidy. Prost. Kompleks. Soyed. (Lanthanides. Simple Complex Compd) [in Russian]. RGU: Rostov-on-Don, 1980.

  2. S. N. Ivanin, V. Yu. Buz′ko, A. I. Goryachko, and V. T. Panyushkin. Russ. J. Inorg. Chem., 2020, 65(6), 880-886.

    Article  CAS  Google Scholar 

  3. S. N. Ivanin, V. Yu. Buz′ko, A. I. Goryachko, and V. T. Panyushkin. Russ. J. Phys. Chem., A, 2020, 94(8), 1623-1627.

    Article  CAS  Google Scholar 

  4. S. Ghosh, C. Gómez García, J. Clemente-Juan, and A. Ghosh. Magnetochemistry, 2015, 2(1), 2.

    Article  CAS  Google Scholar 

  5. M. Almáši, A. Zeleňáková, I. Císařová, J. Bednarčík, and V. Zeleňák. Acta Phys. Pol., A, 2014, 126(1), 308-309.

    Article  Google Scholar 

  6. J. Lu, X. Li, G. Skorupskii, L. Sun, B. K. Ofori-Okai, M. Dinca, and K. A. Nelson. Chem. Sci., 2017, 8(11), 7312-7323.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  7. J. A. Clayton, K. Keller, M. Qi, J. Wegner, V. Koch, H. Hintz, and M. Yulikov. Phys. Chem. Chem. Phys., 2018, 20(15), 10470-10492.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  8. G. P. Vishnevskaya, E. N. Frolova, and A. M. Gataullin. Phys. Solid State, 2003, 45(5), 859-863.

    Article  CAS  Google Scholar 

  9. G. P. Vishnevskaya, E. N. Frolova, and A. R. Fakhrutdinov. Russ. J. Phys. Chem., 2002, 76(5), 773-781.

  10. N. Ishikawa, N. Tanaka, and Y. Kaizu. Inorg. Chim. Acta, 2004, 357(7), 2181-2184.

    Article  CAS  Google Scholar 

  11. R. S. de Biasi and M. L. N. Grillo. J. Phys. Chem. Solids, 2004, 65(6), 1207-1209.

    Article  CAS  Google Scholar 

  12. G. Leniec, S. M. Kaczmarek, J. Typek, B. Kołodziej, E. Grech, and W. Schilf. J. Phys.: Condens. Matter, 2006, 18(43), 9871-9880.

    Article  CAS  Google Scholar 

  13. A. A. Ryadun, E. N. Galashov, V. A. Nadolinny, and V. N. Shlegel. J. Struct. Chem., 2012, 53(4), 685-689.

    Article  CAS  Google Scholar 

  14. A. A. Prokhorov. Fiz. Tekh. Vys. Davlenii, 2013, 23(1), 30-36.

  15. T. P. Gavrilova, R. M. Eremina, I. V. Yatsyk, I. I. Fazlizhanov, A. A. Rodionov, D. V. Mamedov, N. V. Andreev, V. I. Chichkov, and Ya. M. Mukovsky. JETP Lett., 2013, 98(7), 380-383

    Article  CAS  Google Scholar 

  16. A. M. Sinicin, R. R. Zainullin, and V. A. Ulanov. Izv. Vyssh. Uchebn. Zaved., Probl. Energ., 2018, 20(7-8), 124-135.

  17. S. A. Altshuler and B. M. Kozyrev. Elektron. Paramagnit. Rezonans Soyed. Element. Promezhut. Grupps (Electron. Paramagn. Reson. Compd. Elem. Intermed. Groups) [in Russian]. Nauka: Moscow, 1972.

  18. J. S. Li, X. D. Sun, S. H. Liu, D. Huo, X. D. Li, J. G. Li, and M. Zhang. Key Eng. Mater., 2013, 544, 3-7.

    Article  Google Scholar 

  19. R. K. Shukla, T. B. Singh, and M. Shukla. J. Chem. Chem. Sci., 2016, 6(11), 1029-1036.

  20. M. K. Mukhopadhyay, M. K. Sanyal, A. Datta, J. Webster, and J. Penfold. Chem. Phys. Lett., 2005, 407(4-6), 276-282.

    Article  CAS  Google Scholar 

  21. M. A. Al-Anber, H. M. Daoud, T. Rüffer, and H. Lang. Arabian J. Chem., 2016, 9(3), 344-349.

    Article  CAS  Google Scholar 

  22. M. A. Al-Anber and H. Daoud. Orient. J. Chem., 2013, 29(3), 905-909.

    Article  CAS  Google Scholar 

  23. S. Stoll and A. Schweiger. J. Magn. Reson., 2006, 178(1), 42-55.

    Article  CAS  PubMed  Google Scholar 

  24. S. Stoll and A. Schweiger. Biol. Magn. Reson., 2007, 27, 299-321.

  25. V. Singh, G. Sivaramaiah, J. L. Rao, and S. H. Kim. J. Lumin., 2013, 143, 162-168.

    Article  CAS  Google Scholar 

  26. G. SivaRamaiah and J. LakshmanaRao. J. Alloys Compd., 2013, 551, 399-404.

    Article  CAS  Google Scholar 

  27. J. A. Weil, J. R. Bolton, and J. E. Wertz. Electron Paramagn. Reson. Elem.Theory Pract. Appl. Wiley: New York, 1994.

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Funding

The work was performed using the facilities of the Center “Structure Diagnostics and Properties of Nanomaterials” of the Kuban State University with the support of the Ministry of Science and Education of the Russian Federation (State contract FZEN-2020-0022).

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Authors and Affiliations

  1. Kuban State University, Krasnodar, Russia

    S. N. Ivanin, V. Yu. Buz’ko, M. E. Sokolov & V. T. Panyushkin

  2. Chechen State University, Grozny, Russia

    M. A. Magomadova

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  1. S. N. Ivanin
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  2. V. Yu. Buz’ko
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  3. M. E. Sokolov
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  4. M. A. Magomadova
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  5. V. T. Panyushkin
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Correspondence to S. N. Ivanin.

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The authors declare that they have no conflict of interests.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 4, pp. 602-610.https://doi.org/10.26902/JSC_id71136

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Ivanin, S.N., Buz’ko, V.Y., Sokolov, M.E. et al. STRUCTURE AND PROPERTIES OF THE MIXED-LIGAND COMPLEX COMPOUND OF GADOLINIUM STEARATE WITH BENZOYLTRIFLUOROACETONE. J Struct Chem 62, 563–570 (2021). https://doi.org/10.1134/S0022476621040077

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  • DOI: https://doi.org/10.1134/S0022476621040077

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