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Optical and Magnetic Properties of a Heteroligand Complex of Gadolinium Stearate with Acetyl Acetone

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Abstract

A heteroligand complex of gadolinium stearate with acetylacetone is synthesized. Its composition is determined via thermogravimetry and energy dispersive analysis. Scanning electron microscopy shows that the synthesized material consists of layered particles with an average size of 50–60 μm. According to data from X-ray phase analysis, the complex of gadolinium stearate with acetylacetone has a tetragonal crystal lattice with parameters a = b = 24.03 Å and c = 27.81 Å. Diffuse light reflectance spectra of the complex are used to determine its band gap (3.04 eV). The magnetic susceptibility of the complex in the 2 MHz–2.5 GHz range is calculated from the experimentally measured impedances using a vector network analyzer.

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REFERENCES

  1. Z. A. Taha, A. M. Ajlouni, A. K. Hijazi, et al., J. Lumin. 161, 229 (2015). https://doi.org/10.1016/j.jlumin.2015.01.013

    Article  CAS  Google Scholar 

  2. C. C. L. Pereira, J. T. Coutinho, L. C. J. Pereira, et al., Polyhedron 91, 42 (2015). https://doi.org/10.1016/j.poly.2015.02.026

    Article  CAS  Google Scholar 

  3. J. S. Kang, Y. K. Jeong, Y. S. Shim, et al., J. Lumin. 178, 368 (2016). https://doi.org/10.1016/j.jlumin.2016.06.008

    Article  CAS  Google Scholar 

  4. W. M. Wang, X. F. Guan, X. D. Liu, et al., Inorg. Chem. Commun. 79, 8 (2017). https://doi.org/10.1016/j.inoche.2017.03.014

    Article  CAS  Google Scholar 

  5. A. Arauzo, A. Lazaresc, S. Shova, et al., Dalton Trans. 43, 12342 (2014). https://doi.org/10.1039/c4dt01104j

    Article  CAS  PubMed  Google Scholar 

  6. Y. M. Litvinova, N. V. Kuratieva, and Y. M. Gayfulin, Polyhedron 102, 27 (2015). https://doi.org/10.1016/j.poly.2015.07.059

    Article  CAS  Google Scholar 

  7. M. Machata, R. Herchel, I. Nemec, et al., Dalton Trans. 46, 16294 (2017). https://doi.org/10.1039/c7dt03441e

    Article  CAS  PubMed  Google Scholar 

  8. J. Zhang, Y. Ye, Y. Chen, et al., J. Am. Chem. Soc. 136, 2630 (2014). https://doi.org/10.1021/ja412254k

    Article  CAS  PubMed  Google Scholar 

  9. D. I. Alexandropoulos, K. R. Vignesh, B. S. Dolinar, et al., Polyhedron 151, 255 (2018). https://doi.org/10.1016/j.poly.2018.04.034

    Article  CAS  Google Scholar 

  10. V. V. Lukov, V. A. Kogan, S. I. Levchenkov, I. N. Shcherbakov, and L. D. Popov, Russ. J. Coord. Chem. 41, 1 (2015). https://doi.org/10.7868/S0132344X15010053

    Article  CAS  Google Scholar 

  11. S. N. Ivanin, V. Yu. Buz’ko, A. I. Goryachko, and V. T. Panyushkin, Russ. J. Inorg. Chem. 65, 880 (2020).

    Article  CAS  Google Scholar 

  12. J. Li, X. Sun, S. Liu, et al., Key Eng. Mater. 544, 3 (2013). doi 10.4028/www.scientific.net/kem.544.3

  13. R. M. Mahfouz, G. A.-W. Ahmed, and M. R. Alshammari, Radiat Eff. Defects Solids 169, 490 (2014). https://doi.org/10.1080/10420150.2013.877909

    Article  CAS  Google Scholar 

  14. R. A. Lalancette, D. Syzdek, J. Grebowicz, et al., J. Therm. Anal. Calorim. (2018). https://doi.org/10.1007/s10973-018-7598-8

  15. R. V. Shpanchenko and M. G. Rozova, X-ray Phase Analysis (Mosk. Gos. Univ., Moscow, 1998) [in Russian].

    Google Scholar 

  16. S. Bock, C. Kijatkin, D. Berben, et al., Appl. Sci. 9, 4933 (2019). https://doi.org/10.3390/app9224933

    Article  CAS  Google Scholar 

  17. R. López and R. Gómez, J. Sol-Gel Sci. Technol. 61, 1 (2012). https://doi.org/10.1007/s10971-011-2582-9

    Article  CAS  Google Scholar 

  18. R. Dosoudil and V. Olah, J. Electric. Eng. 55 (10/S), 97 (2004).

  19. V. Radonić, N. Blaž, and Lj. Živanov, Acta Phys. Polon., A 117, 820 (2010).

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Authors and Affiliations

  1. Kuban State University, 350040, Krasnodar, Russia

    S. N. Ivanin, V. Yu. Buzko, A. I. Goryachko & V. T. Panyushkin

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  1. S. N. Ivanin
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  2. V. Yu. Buzko
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  3. A. I. Goryachko
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  4. V. T. Panyushkin
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Correspondence to S. N. Ivanin.

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Ivanin, S.N., Buzko, V.Y., Goryachko, A.I. et al. Optical and Magnetic Properties of a Heteroligand Complex of Gadolinium Stearate with Acetyl Acetone. Russ. J. Phys. Chem. 95, 326–331 (2021). https://doi.org/10.1134/S0036024421020114

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  • DOI: https://doi.org/10.1134/S0036024421020114

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