Skip to main content
SpringerLink
Log in

MIXED-LIGAND NITROSYL AND 3-CYANOPYRIDINE COMPLEX OF RUTHENIUM(II): SYNTHESIS, CRYSTAL STRUCTURE, AND BOND ISOMERISM

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The [RuNO(3-CNPy)2Cl3] complex is obtained in the reaction of K2[RuNOCl5] with 3-cyanopyridine. The compound is characterized by the elemental analysis and IR spectroscopy; its crystal structure is investigated by single crystal X-ray diffraction. Crystallographic data are: Р21/c, a = 8.1487(3) Å, b = 14.8118(6) Å, c = 13.0364(5) Å, α = 90°, β = 101.966(1)°, γ = 90°, V = 1539.26(10) Å3, Z = 4, R = 0.0256. The complex is obtained as a facial isomer where chlorine atoms occupy one of the faces of a distorted {RuN3Сl3} octahedron. Photochemical isomerization (λ = 445 nm, 100 mW) at 80 K leads to the formation of a bond isomer with occupancy of 17% and coordination of the nitrosyl group through an oxygen atom. At temperatures above 170 K in the absence of radiation a reverse reaction occurs with the formation of a main isomer with coordination of the nitrosyl group through the nitrogen atom. Activation parameters of this process are determined by IR spectroscopy: Ea= 46.5(1.7) kJ/mol and lgk0 = 10.8(1.0).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

REFERENCES

  1. E. Alessio and L. Messori. Molecules, 2019, 24, 1995.

  2. A. A. Shushakov, I. P. Pozdnyakov, V. P. Grivin, V. F. Plyusnin, D. B. Vasilchenko, A. V. Zadesenets, A. A. Melnikov, S. V. Chekalin, and E. M. Glebov. Dalton Trans., 2017, 46, 9440.

  3. D. B. Vasilchenko, A. V. Zadesenets, I. A. Baidina, D. A. Piryazev, and G. V. Romanenko. J. Struct. Chem., 2017, 58(8), 1689.

  4. N. Sadeghi, R. Ghiasi, and S. Jamehbozorgi. J. Struct. Chem., 2018, 59(8), 1791.

  5. O. E. Polozhentsev, V. K.Kochkina, V. L. Mazalova, and A. V. Soldatov. J. Struct. Chem., 2016, 57(7), 1477.

  6. G. A. Kostin, A. A. Mikhailov, N. V. Kuratieva, D. P. Pischur, D. O. Zharkov, and I. R. Grin. New J. Chem., 2017, 41, 7758.

  7. A. A. Mikhailov, D. V. Khantakova, V. A. Nichiporenko, E. M. Glebov, V. P. Grivin, V. F. Plyusnin, V. V. Yanshole, D. V. Petrova, G. A. Kostin, and I. R. Grin. Metallomics, 2019, 11, 1999.

  8. A. A. Mikhailov, V. A. Vorobyev, V. A. Nadolinny, Y. V. Patrushev, Y. S. Yudina, and G. A. Kostin. J. Photochem. Photobiol., A, 2019, 373, 37.

  9. B. Cormary, S. Ladeira, K. Jacob, P. G. Lacroix, T. Woike, D. Schaniel, and I. Malfant. Inorg. Chem., 2012, 51, 7492.

  10. A. A. Mikhailov, E. Wenger, G. A. Kostin, and D. Schaniel. Chem. – Eur. J., 2019, 25, 7569.

  11. A. Mikhailov, V. Vuković, C. Kijatkin, E. Wenger, M. Imlau, T. Woike, G. Kostin, and D. Schaniel. Acta Crystallogr. Sect. B: Struct. Sci. Cryst. Eng. Mater., 2019, 75, 1152.

  12. G. M. Sheldrick. Acta Crystallogr., Sect. A: Found. Crystallogr., 2015, 71, 3.

  13. V. Vorobyev, G. A. Kostin, I. A. Baidina, A. A. Mikhailov, I. V. Korolkov, and V. A. Emelyanov. Z. Anorg. Allg. Chem., 2020, 646, 58.

  14. G. te Velde, F. M. Bickelhaupt, E. J. Baerends, C. Fonseca Guerra, S. J. A. van Gisbergen, J. G. Snijders, and T. Ziegler. J. Comput. Chem., 2001, 22, 931.

  15. J. P. Perdew, K. Burke, and M. Ernzerhof. Phys. Rev. Lett., 1996, 77, 3865.

  16. A. D. Becke. Phys. Rev. A, 1988, 38, 3098.

  17. E. Van Lenthe and E. J. Baerends. J. Comput. Chem., 2003, 24, 1142.

  18. A. Kumar, R. Pandey, R. K. Gupta, K. Ghosh, and D. S. Pandey. Polyhedron, 2013, 52, 837.

  19. D. S. Bohle and E. S. Sagan. Eur. J. Inorg. Chem., 2000, 3, 1609.

  20. A. N. Makhinya, M. A. Il′in, R. D. Yamaletdinov, I. A. Baidina, S. V. Tkachev, A. P. Zubareva, I. V. Korol′kov, and D. A. Piryazev. Russ. J. Coord. Chem., 2016, 42, 768.

  21. E. D. Rechitskaya, N. V Kuratieva, E. V Lider, J. A. Eremina, L. S. Klyushova, I. V Eltsov, and G. A. Kostin. J. Mol. Struct., 2020, 1219, 128565, DOI: 10.1016/j.molstruc.2020.128565.

  22. M. A. Il′in, V. A. Emel′yanov, and I. A. Baidina. J. Struct. Chem., 2008, 49(6), 1090.

  23. V. Vorobyev, V. A. Emelyanov, O. A. Plusnina, E. M. Makarov, I. A. Baidina, A. I. Smolentsev, S. V. Tkachev, and T. I. Asanova. Eur. J. Inorg. Chem., 2017, 2017, 971.

  24. V. Vorobyev, A. A. Mikhailov, V. Y. Komarov, A. N. Makhinya, and G. A. Kostin. New J. Chem., 2020, 44, 4762.

  25. V. Vorobyev, N. I. Alferova, and V. A. Emelyanov. Inorg. Chem., 2019, 58, 1007.

  26. Y. Morioka, A. Ishikawa, H. Tomizawa, and E. Miki. J. Chem. Soc., Dalton Trans., 2000, 54, 781.

  27. V. Vorobyev, G. A. Kostin, N. V. Kuratieva, and V. A. Emelyanov. Inorg. Chem., 2016, 55, 9158.

  28. V. Vorobyev, D. S. Budkina, and A. N. Tarnovsky. J. Phys. Chem. Lett., 2020, 11, 4639.

  29. J. Sanz García, F. Alary, M. Boggio-Pasqua, I. M. Dixon, I. Malfant, and J.-L. Heully. Inorg. Chem., 2015, 54, 8310.

  30. F. Talotta, L. González, and M. Boggio-Pasqua. Molecules, 2020, 25, 2613.

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    E. D. Rechitskaya, V. A. Vorobiev, N. V. Kuratieva & G. A. Kostin

Authors
  1. E. D. Rechitskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Vorobiev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Kuratieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. A. Kostin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. A. Kostin.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Translated from Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 2, pp. 270-279 https://doi.org/10.26902/JSC_id68344 .

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Rechitskaya, E.D., Vorobiev, V.A., Kuratieva, N.V. et al. MIXED-LIGAND NITROSYL AND 3-CYANOPYRIDINE COMPLEX OF RUTHENIUM(II): SYNTHESIS, CRYSTAL STRUCTURE, AND BOND ISOMERISM. J Struct Chem 62, 256–264 (2021). https://doi.org/10.1134/S0022476621020104

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476621020104

Keywords

Search

Navigation