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TWO Co(II)-BASED COORDINATION POLYMERS: STRUCTURAL DIVERSITY AND PREVENTION ACTIVITY ON SKIN NECROSIS AFTER FRACTURE AND INTERNAL FIXATION

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Abstract

Two new cobalt(II) cluster-based 3D coordination polymers [Co2(MeOip)2(bpa)2(H2O)] (1) and [Co5(MeOip)4(μ3-O)(bpp)2(DMF)(H2O)3]·2H2O (2) (MeOip = 5-methoxyisophthalate, bpp = 1,3-bis(4-pyridyl)propane and bpa = 1,2-bi(4-pyridyl)ethane) are synthesized with 5-methoxyisophthalic acid and bpp/bpa mixed ligands. Furthermore, the prevention activity of the compounds on skin necrosis after fracture and its mechanism is evaluated. Firstly, the content level of MCSF and TNF-α is evaluated with the ELISA detection kit. The relative expression level of MMP2 and TIMP1 is measured with real-time RT-PCR.

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Authors and Affiliations

  1. Department of Orthopedics, No. 7 and Orthopedic Hospital, Zibo, Shandong, P. R. China

    W. -J. Wang

  2. Department of Orthopedics, Shandong Wendeng Osteopathic Hospital, Wendeng, Shandong, P. R. China

    X. -G. Wang

  3. Department of Dermatology, The Second Hospital of Dalian Medical University, Dalian, Liaoning, P. R. China

    B. -B. Hou

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  1. W. -J. Wang
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  2. X. -G. Wang
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  3. B. -B. Hou
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Correspondence to B. -B. Hou.

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Wang, W.J., Wang, X.G. & Hou, B.B. TWO Co(II)-BASED COORDINATION POLYMERS: STRUCTURAL DIVERSITY AND PREVENTION ACTIVITY ON SKIN NECROSIS AFTER FRACTURE AND INTERNAL FIXATION. J Struct Chem 61, 1648–1654 (2020). https://doi.org/10.1134/S0022476620100182

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