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CRYSTAL STRUCTURES OF THE FIRST DISELENOPHOSPHINATE MOLYBDENUM(II) ALLYL COMPLEXES: [Mo(CH3CN)(κ3-C3H5)](CO)2(κ2-Se2PPh2)] AND [Mo(κ3-C3H5)(CO)2(κ2-Phen)(κ1-Se2PPh2)]

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Abstract

A reaction of [Mo(CH3CN)2(κ3-C3H5)(CO)2(Br)] (complex 1) and (Et4N)[Se2PPh2] (complex 2) produces a κ2-diselenophosphinate molybdenum [Mo(CH3CN)(κ3-C3H5)(CO)2(κ2-Se2PPh2)] complex (complex 3). Treatment of 3 with 1,10-phenanthroline, C12H8N2, yields a κ1-diselenophosphinate [Mo(κ3-C3H5)(CO)2(κ2-Phen)(κ1-Se2PPh2)] complex (complex 4). The coordination geometry around the molybdenum atom of complexes 3 and 4 is octahedral with acetonitrile, allyl, two carbonyls, and two selenium atoms and allyl, two carbonyls, two nitrogen atoms of the 1,10-phenanthroline ligand, and one selenium atom, occupying six-coordination sites, respectively. To the best of our knowledge, complexes 3 and 4 are the first diselenophosphinate molybdenum allyl complexes. Complexes 3 and 4 are characterized through the elemental analysis, fast atom bombardment mass spectrometry, 31P NMR spectroscopy, and single crystal X-ray diffraction.

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Authors and Affiliations

  1. Department of Applied Chemistry, Providence University, Taichung City, Taiwan

    Y. -S. Lin & K. -F. Huang

  2. Instrumentation Center, College of Science, National Taiwan University, Taiwan

    G. -H. Lee

  3. Department of Applied Cosmetology, Hungkuang University, Taichung City, Taiwan

    K. -H. Yih

  4. Department of Hair Styling and Design, Hungkuang University, Taichung City, Taiwan

    H. -F. Wang

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  1. Y. -S. Lin
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  2. G. -H. Lee
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  3. K. -H. Yih
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  5. K. -F. Huang
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Correspondence to H. -F. Wang or K. -F. Huang.

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Lin, Y.S., Lee, G.H., Yih, K.H. et al. CRYSTAL STRUCTURES OF THE FIRST DISELENOPHOSPHINATE MOLYBDENUM(II) ALLYL COMPLEXES: [Mo(CH3CN)(κ3-C3H5)](CO)2(κ2-Se2PPh2)] AND [Mo(κ3-C3H5)(CO)2(κ2-Phen)(κ1-Se2PPh2)]. J Struct Chem 61, 1439–1445 (2020). https://doi.org/10.1134/S0022476620090115

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