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A STUDY OF CRYSTAL STRUCTURES OF TETRA(p-TOLYL)ANTIMONY 2,4,6-TRICHLOROPHENOXIDE AND 3,4,5-TRIFLUOROBENZOATE

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Abstract

Tetra(p-tolyl)antimony 2,4,6-trichlorophenoxide p-Tol4SbOC6H2Cl3-2,4,6 (1) and tetra(p-tolyl)antimony 3,4,5-trifluorobenzoate p-Tol4SbOС(O)C6H2F3-3,4,5 (2) are synthesized by the interaction of penta(p-tolyl)antimony with equimolar amounts of 2,4,6-trichlorophenol and 3,4,5-trifluorobenzoic acid in a benzene solution. Compounds 1 and 2 are also obtained by ligand redistribution reactions between penta(p-tolyl)antimony and symmetric antimony derivatives p-Tol3SbХ2. The crystal structures and structural features of compounds 1 and 2, in which antimony atoms have a trigonal bipyramidal coordination of substituents with axially located oxygen-containing ligands, are determined by single crystal X-ray diffraction.

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  1. South Ural State University, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & A. N. Efremov

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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Sharutin, V.V., Sharutina, O.K. & Efremov, A.N. A STUDY OF CRYSTAL STRUCTURES OF TETRA(p-TOLYL)ANTIMONY 2,4,6-TRICHLOROPHENOXIDE AND 3,4,5-TRIFLUOROBENZOATE. J Struct Chem 61, 1414–1421 (2020). https://doi.org/10.1134/S0022476620090085

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