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CRYSTAL STRUCTURE AND PHYSICAL PROPERTIES OF A NEW ONE-DIMENSIONAL POLYMER BASED ON 1,3,5-TRIS(2-METHYLIMIDAZOL-1-YL)BENZENE AND 5-NITRO-1,3-BENZENEDICARBOXYLIC ACID

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Abstract

A one-dimensional Co(II) complex {[Co2(TIMB)(NO2–IPA)2(H2O)2]·H2O}n (1) (TIMB = 1,3,5-tris(2-methylimidazol-1-yl)benzene, NO2–H2IPA = 5-nitro-1,3-benzenedicarboxylic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis. The single crystal X-ray diffraction analysis reveals that 1 is a 1D polymeric loop chain based on [Co4(NO2–IPA)4] and [Co2(TIMB)2] loops. Complex 1 exhibits an emission band at 358 nm (λex = 322 nm) and good catalytic photodegradation of RhB. Furthermore, there are antiferromagnetic interactions between the magnetic Co(II) centers in 1.

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Authors and Affiliations

  1. School of Chemistry and Environmental Engineering, Yancheng Teachers University, Yancheng, Jiangsu, P.R. China

    X. -Y. Zhang, M. -L. Xu, J. -P. Wu & J. Wang

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  1. X. -Y. Zhang
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  2. M. -L. Xu
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  3. J. -P. Wu
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  4. J. Wang
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Correspondence to J. Wang.

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Zhang, X.Y., Xu, M.L., Wu, J.P. et al. CRYSTAL STRUCTURE AND PHYSICAL PROPERTIES OF A NEW ONE-DIMENSIONAL POLYMER BASED ON 1,3,5-TRIS(2-METHYLIMIDAZOL-1-YL)BENZENE AND 5-NITRO-1,3-BENZENEDICARBOXYLIC ACID. J Struct Chem 61, 1398–1404 (2020). https://doi.org/10.1134/S0022476620090061

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