Skip to main content
SpringerLink
Log in

Spin-Labeled Linker for the Design of Coordination Polymers

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The synthesis of a novel nitronylnitroxyl radical 2-(2,5-di(pyridin-4-yl)phenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-3-oxide-1-oxyl (L) and the first Mn(II) complex with it [Mn(NO3)2(L)(H2O)× ×(i-PrOH)] is elaborated and performed. It is found that the complex is formed by polymeric chains in which (NO3)2(H2O)(i-PrOH) fragmentы are linked by L coordinated by N atoms of pyridine rings. The chains are combined into layers by hydrogen bonds between the coordinated water molecules, i-PrOH, and nitrate anions. The layers are joined into a framework by weak C-H⋯O contacts between O atoms of the nitronylnitroxyl fragment and the pyridine C-H group.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. Z. Moghadam, A. Li, S. B. Wiggin, A. Tao, A. G. P. Maloney, P. A. Wood, S. C. Ward, and D. Fairen-Jimenez. Chem. Mater., 2017, 29, 2618.

    Article  CAS  Google Scholar 

  2. G. Maurin, C. Serre, A. Cooper, and G. Férey. Chem. Soc. Rev., 2017, 46, 3104.

    Article  CAS  Google Scholar 

  3. S. Yuan, L. Feng, K. Wang, J. Pang, M. Bosch, C. Lollar, Y. Sun, J. Qin, X. Yang, P. Zhang, Q. Wang, L. Zou, Y. Zhang, L. Zhang, Y. Fang, J. Li, and H.-C. Zhou. Adv. Mater., 2018, 30, 1704303.

    Article  CAS  Google Scholar 

  4. V. R. Remya and M. Kurian. Int. Nano Lett., 2019, 9, 17.

    Article  CAS  Google Scholar 

  5. V. F. Cheong and P. Y. Moh. Mater. Sci. Technol., 2018, 3(9), 1025.

    Article  CAS  Google Scholar 

  6. G. M. Espallargas and E. Coronado. Chem. Soc. Rev., 2018, 47, 533.

    Article  Google Scholar 

  7. T. B. Faust and D. M. D’Alessandro. RSC Adv., 2014, 4, 17498.

    Article  CAS  Google Scholar 

  8. E. Coronado. Nat. Rev. Mater., 2019, 5, 87.

    Google Scholar 

  9. J. S. Miller. Mater. Today, 2014, 17, 224.

    Article  CAS  Google Scholar 

  10. E. Moreno-Pineda, C. Godfrin, F. Balestro, W. Wernsdorfer, and M. Ruben. Chem. Soc. Rev., 2018, 47, 501.

    Article  CAS  Google Scholar 

  11. G. Molnár, S. Rat, L. Salmon, W. Nicolazzi, and A. Bousseksou. Adv. Mater., 2018, 30, 1703862.

    Google Scholar 

  12. S. Sanvito. Chem. Soc. Rev., 2011, 40, 3336.

    Article  CAS  Google Scholar 

  13. A. Forment-Aliaga and E. Coronado. Chem. Rec., 2018, 18, 737.

    Article  CAS  Google Scholar 

  14. L. Sun, M. G. Campbell, and M. Dinca. Angew. Chem., Int. Ed., 2016, 55, 3566.

    Article  CAS  Google Scholar 

  15. L. S. Xie, L. Sun, R. Wan, S. S. Park, J. A. DeGayner, C. H. Hendon, and M. Dincă. J. Am. Chem. Soc., 2018, 140, 7411.

    Article  CAS  Google Scholar 

  16. M. L. Aubrey, B. M. Wiers, S. C. Andrews, T. Sakurai, S. E. Reyes-Lillo, S. M. Hamed, C.-J. Yu, L. E. Darago, J. A. Mason, J.-O. Baeg, F. Grandjean, G. J. Long, S. Seki, J. B. Neaton, P. Yang, and J. R. Long. Nat. Mater., 2018, 17, 625.

    CAS  Google Scholar 

  17. E. Coronado and G. Mínguez Espallargas. Chem. Soc. Rev., 2013, 42, 1525.

    Article  CAS  Google Scholar 

  18. E. Coronado, M. Giménez-Marqués, G. Mínguez Espallargas, F. Rey, and I. J. Vitórica-Yrezábal. J. Am. Chem. Soc., 2013, 135, 15986.

    Article  CAS  Google Scholar 

  19. A. Abhervé, T. Grancha, J. Ferrando-Soria, M. Clemente-León, E. Coronado, J. C. Waerenborgh, F. Lloreta, and E. Pardo. Chem. Commun., 2016, 52, 7360.

    Article  CAS  Google Scholar 

  20. K. S. Pedersen, P. Perlepe, M. L. Aubrey, D. N. Woodruff, S. E. Reyes-Lillo, A. Reinholdt, L. Voigt, Z. Li, K. Borup, M. Rouzières, D. Samohvalov, F. Wilhelm, A. Rogalev, J. B. Neaton, J. R. Long, and R. Clérac. Nat. Chem., 2018, 10, 1056.

    CAS  Google Scholar 

  21. V. N. Ikorskii, V. I. Ovcharenko, Y. G. Shvedenkov, G. V. Romanenko, S. V. Fokin, and R. Z. Sagdeev. Inorg. Chem., 1998, 37, 4360.

    Article  CAS  Google Scholar 

  22. V. Ovcharenko and E. Bagryanskaya. In: Spin-Crossover Materials: Properties and Applications / Ed. M. A. Halcrow. Wiley & Sons, 2013, 239–280.

  23. J. Linares, E. Codjovi, and Y. Garcia. Sensors, 2012, 12, 4479.

    Article  CAS  Google Scholar 

  24. Cambridge Structural Database. Ver. 5.40 (Nov. 2018, last updates Aug. 2019). University of Cambridge: UK, 2018–2019.

  25. Z. Ju, W. Yan, X. Gao, Z. Shi, T. Wang, and H. Zheng. Cryst. Growth Des., 2016, 16, 2496.

    Article  CAS  Google Scholar 

  26. O. Alduhaish, R.-B. Lin, H. Wang, B. Li, H. D. Arman, T.-L. Hu, and B. Chen. Cryst. Growth Des., 2018, 18, 4522.

    Article  CAS  Google Scholar 

  27. J. Kan, CSD Communication, 2016 (CCDC 150430; 1504304).

  28. K. Shen, Z. Ju, L. Qin, T. Wang, and H. Zheng. Dyes Pigm., 2017, 136, 515.

    Article  CAS  Google Scholar 

  29. K. Takaoka, M. Kawano, M. Tominaga, and M. Fujita. Angew. Chem., Int. Ed., 2005, 44, 2151.

    Article  CAS  Google Scholar 

  30. K. Takaoka, M. Kawano, T. Hozumi, S. Ohkoshi, and M. Fujita. Inorg. Chem., 2006, 45, 3976.

    Article  CAS  Google Scholar 

  31. J. Seo, C. Bonneau, R. Matsuda, M. Takata, and S. Kitagawa. J. Am. Chem. Soc., 2011, 133, 9005.

    Article  CAS  Google Scholar 

  32. X.-G. Guo, Z.-Y. Zhang, S. Qiu, X. Su, Y.-B. Wang, and X. Sun. Chem.-Eur. J., 2017, 23(70), 17727.

    Article  CAS  Google Scholar 

  33. L. Li, R. Matsuda, I. Tanaka, H. Sato, P. Kanoo, H. J. Jeon, M. L. Foo, A. Wakamiya, Y. Murata, and S. Kitagawa. J. Am. Chem. Soc., 2014, 136, 7543.

    Article  CAS  Google Scholar 

  34. J. T. Culp, C. Madden, K. Kauffman, F. Shi, and C. Matranga. Inorg. Chem., 2013, 3(8), 4205.

    Article  CAS  Google Scholar 

  35. V. I. Ovcharenko, C. B. Fokin, G. V. Romanenko, I. V. Korobkov, and P. Re. Izv. Akad. Nauk, Ser. Khim., 1999, 1539.

  36. G. M. Sheldrick. Acta Crystallogr. Sect. C, 2015, 71, 3.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

G. V. Romanenko and A. S. Bogomyakov are thankful to RFBR (18-29-04002) for supporting the magnetochemical and structural studies.

Funding

This study was supported by the Russian Science Foundation (grant 18-13-00380).

Author information

Authors and Affiliations

  1. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    G. V. Romanenko, S. V. Fokin, S. E. Tolstikov, G. A. Letyagin, A. S. Bogomyakov & V. I. Ovcharenko

  2. Novosibirsk State University, Novosibirsk, Russia

    G. A. Letyagin & A. S. Bogomyakov

Authors
  1. G. V. Romanenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Fokin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. E. Tolstikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. A. Letyagin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. S. Bogomyakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. I. Ovcharenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. V. Romanenko.

Ethics declarations

The authors declare that they have no conflict of interests.

Additional information

Russian Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 6, pp. 959–965.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Romanenko, G.V., Fokin, S.V., Tolstikov, S.E. et al. Spin-Labeled Linker for the Design of Coordination Polymers. J Struct Chem 61, 906–913 (2020). https://doi.org/10.1134/S0022476620060104

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476620060104

Keywords

Search

Navigation