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Structural and Mössbauer Studies of Sr1.5Ca1.5Fe2.25Mo0.75O9−δ and Sr1.92Ca1.08Fe2.04W0.96O9−δ Double Perovskites

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Abstract

Sr1.50Ca1.50Fe2.25Mo0.75O9−δ and Sr1.92Ca1.08Fe1.04W0.96O9−δ double perovskites are synthesized in the polycrystalline form by a solid-state reaction route in air and studied at room temperature using the of PXRD, Raman and Mössbauer spectroscopy techniques. The Rietveld refinement analysis reveals that both compounds adopt a tetragonal system with the space group I4/m and lattice parameters a = b = 5.5176(1) Å and c = 7.8065(2) Å for Sr1.50Ca1.50Fe2.25Mo0.75O9−δ and a = b = 5.5453(1) Å and c = 7.8388(1) Å for Sr1.92Ca1.08Fe2.04W0.96O9−δ. Raman spectra are consistent with the group theoretical analysis predicted for tetragonal symmetry I4/m (point group C 54h ). 57Fe Mössbauer spectra recorded at room temperature show a paramagnetic behavior for Sr1.50Ca1.50Fe2.25Mo0.75O9−δ, and magnetic ordering for Sr1.92Ca1.08Fe2.04W0.96O9−δ. The isomer shift (δ) and quadrupole splitting (Δ) values are characteristic of high-spin Fe3+ in a distorted octahedral coordination.

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Authors and Affiliations

  1. Laboratoire Rayonnement-Matiere et Instrumentation, S3M, FST, University Hassan 1er, Settat, Morocco

    A. El Hachmi, B. Manoun & S. Louihi

  2. Materials Science and Nano Engineering (MSN), University Mohammed VI Polytechnic, Ben Guerir, Morocco

    B. Manoun & Y. Tamraoui

  3. Département Matériaux et Procédés, ENSAM Meknès, Université Moulay Ismail, Meknès, Marocco

    L. Bih

  4. Material Physics Laboratory, Faculty of Sciences and Techniques, Sultan Moulay Sliman University, Beni-Mellal, Morocco

    M. Sajieddine

  5. Department of Earth Sciences, Uppsala University, Uppsala, Sweden

    P. Lazor

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  1. A. El Hachmi
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  2. B. Manoun
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  3. Y. Tamraoui
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  4. S. Louihi
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  6. M. Sajieddine
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  7. P. Lazor
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Correspondence to A. El Hachmi.

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Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 6, pp. 913–924.

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El Hachmi, A., Manoun, B., Tamraoui, Y. et al. Structural and Mössbauer Studies of Sr1.5Ca1.5Fe2.25Mo0.75O9−δ and Sr1.92Ca1.08Fe2.04W0.96O9−δ Double Perovskites. J Struct Chem 61, 861–872 (2020). https://doi.org/10.1134/S0022476620060049

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  • DOI: https://doi.org/10.1134/S0022476620060049

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