Abstract
Graphene materials are synthesized in a thermal plasma jet without using size forming catalysts. The synthesis was performed on a direct current plasma torch operating at 28–30 kW with a pressure of 100–710 Torr. The synthesis products are studied by electron microscopy, X-ray diffraction, and dynamic light scattering. It is found that structures formed in the plasma jet have a flake morphology regardless of the type of the carbon bearing source. Thermodynamic calculations testify a correlation between the temperature profile in the plasma jet and the composition of condensed carbon (redistribution between C60 and C80). The application areas of flaky structures are discussed.
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I. Levchenko, M. Keidar, S. Xu, H. Kersten, and K. Ostrikov. J. Vac. Sci. Technol. B, 2013, 31, 050801.
N. M. Santhosh, G. Filipič, E. Tatarova, O. Baranov, H. Kondo, M. Sekine, M. Hori, K. Ostrikov, and U. Cvelbar. Micromachines, 2018, 9, 565.
A. Bianco, H.-M. Cheng, T. Enoki, Y. Gogotsi, R. H. Hurt, N. Koratkar, T. Kyotani, M. Monthioux, C. R. Park, J. M. D. Tascon, and J. Zhang. Carbon, 2013, 65, 1.
J. Hwang, M. Kim, D. Campbell, H. A. Alsalman, J. Y. Kwak, S. Shivaraman, A. R. Woll, A. K. Singh, R. G. Hennig, S. Gorantla, M. H. Rummeli, and M. G. Spencer. ACS Nano, 2013, 7, 385.
Z. Chen, Y. Qi, X. Chen, Y. F. Zhang, and Z. Liu. Adv. Mater., 2018, 1803639.
H. Tan, D. Wang, Y. Raitses, and Y. Guo. Coatings, 2018, 8, 40.
J. Wu, Y. Shao, B. Wang, K. K. Ostrikov, J. Feng, and Q. Cheng. Plasma Processes Polym., 2016, 13, 1008.
K. Markandan, J. K. Chin, and M. T. T. Tan. J. Mater. Res., 2016, 32, 84.
P. Miranzo, M. Belmonte, and M. I. Osendi. J. Eur. Ceram. Soc., 2018, 38, 5637.
M. Bera and P. K. Maji. MOJ Polym. Sci., 2017, 1, 94.
B. Da Kuanga, L. Xua, L. Liua, W. Hua, and Y. Wua. Appl. Surf. Sci., 2013, 273, 484.
D. Nuvoli, V. Alzari, R. Sanna, S. Scognamillo, J. Alongi, and G. Malucelli. J. Nanopart. Res., 2013, 15, 1512.
A. V. Yeletsky and, B. M. Smirnov. Adv. Phys. Sci., 1996, 166(11), 1198.
M. B. Shavelkina and, R. H. Amirov. Nanosyst.: Phys., Chem., Math., 2019, 10, 102.
M. Hu, Z. Yao, and X. Wang. AIMS Mater. Sci., 2017, 4, 755.
P. Wick, A. E. Louw-Gaume, M. Kucki, H. F. Krug, K. Kostarelos, B. Fadeel, K. A. Dawson, A. Salvati, E. Vázquez, L. Ballerini, M. Tretiach, F. Benfenati, E. Flahaut, E. Gauthier, M. Prato, and A. Bianco. Angew. Chem., Int. Ed., 2014, 53, 7714.
Plasma Diagnostics/Ed. W. Lochte-Holtgreven. North-Holland, Interscience (Wiley): Amsterdam, 1968.
K. O. Johansson, M. P. Head-Gordon, P. E. Schrade, K. R. Wilson, and H. A. Michelsen. Science, 2018, 361, 997.
P. A. Marsh, A. Voet, T. J. Mullens, and L. D. Price. Carbon, 1971, 9, 797.
Formation of Soot Particles/Ed. P. A. Tesner. VNIIGAS: U.S.S.R., 1973.
V. M. Batenin, V. A. Bityurin, V. A. Zhelnin, P. P. Ivanov, S. A. Medin, G. A. Lyubimov, V. R. Satanovsky, and V. L. Turovets. Thermophys. High Temp., 1983, 21(3), 567.
A. G. Merzhanov, M. M. Kitain, U. I. Goldschleger, and A. S. Steinberg. Reports of the USSR Academy of Sciences, 1977, 237(2), 391.
G. V. Belov, V. S. Iorish, and V. S. Yungman. High Temp., 2000, 38, 2, 191.
Thermodynamic Modeling of Chemically Reacting Systems [in Russian]/G. V. Belov and B. G. Trusov. MSTU named after N. E. Bauman: M., 2013, 96.
Aspen Plus. Version 2006.5. Aspen Engineering Suite. Aspen Technology: Cambridge MA, USA.
C. D. Scott. J. Nanosci. Nanotechnol., 2004, 4, 368.
S. A. Esfarjani, S. B. Dworkin, J. Mostaghimi, K. S. Kim, C. T. Kingston, B. Simard, and G. Soucy. J. Phys.: Conf. Ser., 2012, 406, 012011.
S. A. Esfarjani. A Modeling Framework for the Synthesis of Carbon Nanotubes by RF Plasma Technology. PhD thesis. University of Toronto, 2013.
B. J. McBride, M. J. Zehe, and S. Gordon. NASA/TM. 4513, 1993.
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This work was financially supported by the Russian Foundation for Basic Research (18-08-00040, 19-08-00081, 18-08-00306).
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Russian Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 4, pp. 623–630.
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Shavelkina, M.B., Ivanov, P.P., Amirov, R.K. et al. Influence of Temperature Profile on the Composition of Condensed Carbon in a Plasma Jet. J Struct Chem 61, 593–600 (2020). https://doi.org/10.1134/S0022476620040137
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DOI: https://doi.org/10.1134/S0022476620040137