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Crystal Structure and Magnetic Properties of a New Wells-Dawson [β-P2CoW17O62]10− Polyoxoanion

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Abstract

New polyoxometalate (POM) H4Li6[β-P2CoW17O62]·x:H2O (1) is synthesized for the first time. The structure of 1 consists of Wells-Dawson type [β-P2CoW17O62]6− POM connected through [Li6(H2O)6]6+ clusters giving rise to a linear chain. The chemical composition of the newly synthesized polyanion is confirmed via1H, 13C, and 31P NMR, FTIR, UV-Vis, and SEM-EDX as well as magnetic measurements.

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Funding

This work has been carried out during sabbatical leave granted to the author (Prof. Dr. A.M. AlDamen) from the University of Jordan during the academic year 2018–2019. Furthermore, the authors acknowledge Ms. Rola Hassouneh, Mr. Wadah Fares and Mr. Lua’y Al-Nather for their technical help. We also thank the Spanish MINECO (project CTQ2017-87201-P AEI/FEDER, UE) and the Generalidad Valenciana (project Prometeo/2019/076).

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Authors and Affiliations

  1. Department of Chemistry, School of Science, the University of Jordan, Amman, Jordan

    M. A. AlDamen & R. A. Al Qawasmeh

  2. Department of Chemistry, College of Arts and Sciences, Khalifa University, SAN Campus, Abu Dhabi, UAE

    M. O. Sinnokrot

  3. Department of Chemistry, College of Science, University of Tabuk, Tabuk, Saudi Arabia

    S. B. Atta

  4. Department of Chemistry, College of Sciences, University of Sharjah, Sharjah, UAE

    R. A. Al Qawasmeh

  5. Instituto de Ciencia Molecular (ICMol), Dpto. Química Inorgánica, Universidad de Valencia, Paterna, Valencia, Spain

    C. J. Gómez-García

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  1. M. A. AlDamen
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  2. M. O. Sinnokrot
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  3. S. B. Atta
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  4. R. A. Al Qawasmeh
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  5. C. J. Gómez-García
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Correspondence to M. A. AlDamen or C. J. Gómez-García.

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Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 4, pp. 589–595.

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AlDamen, M.A., Sinnokrot, M.O., Atta, S.B. et al. Crystal Structure and Magnetic Properties of a New Wells-Dawson [β-P2CoW17O62]10− Polyoxoanion. J Struct Chem 61, 559–565 (2020). https://doi.org/10.1134/S0022476620040083

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  • DOI: https://doi.org/10.1134/S0022476620040083

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