Abstract
By the interaction of TmCl3 with KFormDipp (FormDipp = N,N′-bis(2,6-diisopropylphenyl)-formamidinate) [Tm(FormDipp)2Cl(THF)] (1) and [KTm(FormDipp)2Cl2]2(2) complexes are obtained. The reaction of 1 with potassium thiophenolate is studied. Its product is found to be [Tm(FormDipp)2(SPh)(THF)] complex (3). The structure of all prepared compounds is determined by single crystal X-ray diffraction of the following solid phases: 1a (P-1) and 1b (P21/n) phases being two solvent-free polymorphs for complex 1; 2·0.5C7H8> and 3·C7H8 phases containing solvate toluene molecules for complexes 2 and 3.
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The work was supported by the Russian Science Foundation (Grant No. 16-13-10294).
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Russian Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 4, pp. 580–588.
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Bashirov, D.A., Kolybalov, D.S., Sukhikh, T.S. et al. Synthesis and Structure of Heteroleptic Tm Bis(Formamidinate) Complexes. J Struct Chem 61, 550–558 (2020). https://doi.org/10.1134/S0022476620040071
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DOI: https://doi.org/10.1134/S0022476620040071