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Complexes of Cobalt and Copper Halides Based on 1,3-Dimethylimidazolium-4-Carboxylate

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Abstract

In the interaction of norzooanemonin 1,3-dimethylimidazolium-4-carboxylate (1) with CuBr2, two types of crystals form: purple [Cu(L)2Br2][CuBr4][CuL4] (2) and light blue [CuL4][CuBr3] (3). In the reaction of 1 with CoCl2 in methanol, neutral complex Co(L)2Cl2 (4) forms. The thermal decomposition of complex 4 is studied. At the first stage of this decomposition, two equivalents of CO2 remove in a range 218–275 °C, and then a two-phase removal of two equivalents of L and the formation of CoCl2 occur.

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Acknowledgments

The study was performed using the equipment of the Multiple-Access Center of Physical Research Methods, Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

Funding

The work was supported by Russian Science Foundation grant No. 17-73-10503.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    S. S. Shapovalov, A. V. Kolos, I. V. Skabitskii, N. P. Simonenko & V. V. Minin

  2. Marshal V. I. Chuikov Moscow South-Eastern School, Moscow, Russia

    A. P. Makhin

Authors
  1. S. S. Shapovalov
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  2. A. V. Kolos
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  3. A. P. Makhin
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  4. I. V. Skabitskii
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  5. N. P. Simonenko
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  6. V. V. Minin
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Corresponding author

Correspondence to S. S. Shapovalov.

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Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 10, pp. 1714–1720.

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Shapovalov, S.S., Kolos, A.V., Makhin, A.P. et al. Complexes of Cobalt and Copper Halides Based on 1,3-Dimethylimidazolium-4-Carboxylate. J Struct Chem 60, 1648–1654 (2019). https://doi.org/10.1134/S002247661910010X

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  • DOI: https://doi.org/10.1134/S002247661910010X

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