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Synthesis and Electrophoretic Concentration of Hydroxyapatite Nanoparticles in Reverse Micelles of Oxyethylated Surfactant

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Abstract

By photon correlation spectroscopy the formation of hydroxyapatite nanoparticles in reverse micelles of oxyethylated surfactant Tergitol NP-4 is studied depending on the solubilization capacity of a micellar solution. Stable organosols are obtained, the electrophoretic concentration and the separation of hydroxyapatite nanoparticles from the surfactant excess and synthesis by-products are performed in the presence of an anionic surfactant AOT. According to the transmission electron microscopy data, the shape of hydroxyapatite nanoparticles is elongated (length 40-80 nm, thickness 5-20 nm), which is well consistent with the n-averaged hydrodynamic diameter determined by photon correlation spectroscopy. The nanoparticles are positively charged; their ζ-potential changes from 10 mV to 42 mV, depending on the surfactant and solvent types.

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Funding

The work was performed within the State Contract of the Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences for basic scientific research.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    T. Yu. Podlipskaya & A. I. Bulavchenko

Authors
  1. T. Yu. Podlipskaya
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  2. A. I. Bulavchenko
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Correspondence to T. Yu. Podlipskaya.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 7, pp. 1179-1189.

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Podlipskaya, T.Y., Bulavchenko, A.I. Synthesis and Electrophoretic Concentration of Hydroxyapatite Nanoparticles in Reverse Micelles of Oxyethylated Surfactant. J Struct Chem 60, 1133–1142 (2019). https://doi.org/10.1134/S0022476619070151

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