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Structural Features And Properties of Heteronuclear Germanium(IV) and Some 3d Metal Complexes with Xylaric Acid and 2,2′-Bipyridine

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Abstract

New coordination compounds of germanium and 3d metals with xylaric acid (H5Xylar) and 2,2′-bipyridine (bipy), which contain tetranuclear xylaratogermanate anion [Fe(bipy)3]2[(OH)2Ge2(μ-HXylar)4Ge2(μ- OH)2]·12Н2О·2CH3CN (I) and [Ni(bipy)3]2[(OH)2Ge2(μ-HXylar)4Ge2(μ-OH)2]·20Н2О·2C2H5OH (II) are synthesized. The complexes are studied by the elemental analysis, thermogravimetry, IR spectroscopy, and X-ray diffraction. To visualize and quantitatively assess hydrogen bonds in I and II the Hiershfeld surface analysis is used.

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Authors and Affiliations

  1. Mechnikov Odessa National University, Odesa, Ukraine

    E. A. Chebanenko, E. E. Martsinko & I. I. Seifullina

  2. Scientific Technological Complex “Institute for Single Crystals”, National Academy of Sciences of Ukraine, Kharkov, Ukraine

    V. V. Dyakonenko & S. V. Shishkina

  3. Karazin Kharkov National University, Kharkov, Ukraine

    S. V. Shishkina

Authors
  1. E. A. Chebanenko
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  2. E. E. Martsinko
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  3. I. I. Seifullina
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  4. V. V. Dyakonenko
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  5. S. V. Shishkina
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Correspondence to E. A. Chebanenko.

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Original Russian Text © 2018 E. A. Chebanenko, E. E. Martsinko, I. I. Seifullina, V. V. Dyakonenko, S. V. Shishkina.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 6, pp. 1514–1520, July-August, 2018.

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Chebanenko, E.A., Martsinko, E.E., Seifullina, I.I. et al. Structural Features And Properties of Heteronuclear Germanium(IV) and Some 3d Metal Complexes with Xylaric Acid and 2,2′-Bipyridine. J Struct Chem 59, 1462–1468 (2018). https://doi.org/10.1134/S0022476618060318

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  • DOI: https://doi.org/10.1134/S0022476618060318

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