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Structural Characterization of a Zinc(II) Bishexafluoroacetylacetonate Coordination Polymer with Bis(4-(1H-Imidazol-1-Yl)Phenyl)Methanone Ligands

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Abstract

A novel zinc complex with the formula [Zn(hfac)2(L1)]n (1) (L1 = bis(4-(1H-imidazol-1-yl)phenyl)methanone) is synthesized and structurally characterized by IR, elemental analyses, and the single crystal X-ray diffraction analysis. The zinc(II) ions of 1 are in a distorted octahedral environment with four O atoms of the hfac ligands and two N atoms from two L1 ligands. Each L1 acts as a bridging ligand to link two Zn(II) atoms to form a helical chain.

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Authors and Affiliations

  1. Department of Applied Chemistry, Yuncheng University, Yuncheng, P. R. China

    G.-F. Wang & S.-W. Sun

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  1. G.-F. Wang
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  2. S.-W. Sun
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Correspondence to G.-F. Wang.

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Original Russian Text © 2018 G.-F. Wang, S.-W. Sun.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 3, pp. 747–750, March-April, 2018.

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Wang, GF., Sun, SW. Structural Characterization of a Zinc(II) Bishexafluoroacetylacetonate Coordination Polymer with Bis(4-(1H-Imidazol-1-Yl)Phenyl)Methanone Ligands. J Struct Chem 59, 725–728 (2018). https://doi.org/10.1134/S0022476618030344

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  • DOI: https://doi.org/10.1134/S0022476618030344

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